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Russian Journal of Physical Chemistry A

, Volume 90, Issue 11, pp 2254–2261 | Cite as

Dynamics of the sorption of phosphatidylcholine by mesoporous composites based on MCM-41

  • L. A. Sinyaeva
  • N. A. BelanovaEmail author
  • S. I. Karpov
  • V. F. Selemenev
  • F. Roessner
Physical Chemistry of Surface Phenomena

Abstract

The possibility of predicting the breakthrough curves of a phospholipid (PL) during its sorption by mesoporous composites based on MCM-41 using models of the dynamics of sorption that consider the kinetics of adsorption (the Thomas model) and mixed diffusion (the asymptotic model) is demonstrated using phosphatidylcholine (PC) as an example. The effect the kinetic parameters have on the tailing of the sorption front with respect to the mixed diffusion limitation of the sorption of nonpolar biologically active substances (BASes) is shown. It is found that the ordered structure of composite materials based on MCM-41 ensures a high rate of mass transfer and thus little tailing of the sorption front, when compared to sorbents with a lower degree of order (silica gel and polymer materials) during the sorption of a phospholipid under dynamic conditions. Based on calculations of the parameter of pattern Λ under the conditions of the dynamic mode of sorption in mixed diffusion kinetics, it is shown that the sorption of phosphatidylcholine from hexane solutions by mesoporous composites based on MCM-41 allows the sorption chromatographic process to proceed in the most advantageous (quasi-equilibrium) mode.

Keywords

biologically active substances phospholipids phosphatidylcholine MCM-41 mesoporous composite intradiffusion kinetics interdiffusion kinetics coefficient of diffusion asymptotic model of the dynamics of sorption Thomas model 

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Copyright information

© Pleiades Publishing, Ltd. 2016

Authors and Affiliations

  • L. A. Sinyaeva
    • 1
  • N. A. Belanova
    • 1
    Email author
  • S. I. Karpov
    • 1
  • V. F. Selemenev
    • 1
  • F. Roessner
    • 2
  1. 1.Faculty of ChemistryVoronezh State UniversityVoronezhRussia
  2. 2.Chemical Technology II, Institute of Pure and Applied Chemistry, Faculty of Mathematics and Natural SciencesUniversity of OldenburgOldenburgGermany

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