Skip to main content

Proton magnetic relaxation study of the thermodynamic characteristics of water adsorbed by cellulose fibers

Abstract

The possibility of determining the thermodynamic parameters that characterize the sorption properties of cellulose and the state of water associated with its fibers is demonstrated using modern concepts of the structure of this vegetable polymer and methods based on theories of adsorption and NMR relaxation in heterogeneous systems.

This is a preview of subscription content, access via your institution.

References

  1. S. Brunauer, P. H. Emmett, and E. Teller, J. Am. Chem. Soc. 60, 309 (1938).

    CAS  Article  Google Scholar 

  2. E. A. Guggenheim, Application of Statistical Mechanics (Clarendon, Oxford, 1966), p. 186.

    Google Scholar 

  3. R. B. Anderson, J. Am. Chem. Soc. 68, 686 (1946).

    CAS  Article  Google Scholar 

  4. J. H. de Boer, The Dynamical Character of Adsorption, 2nd ed. (Clarendon, Oxford, 1953), p. 200.

    Google Scholar 

  5. I. Langmuir, J. Am. Chem. Soc. 38, 2221 (1916).

    CAS  Article  Google Scholar 

  6. S. Gregg and K. Sing, Adsorption, Surface Area, and Porosity (Academic, New York, 1982).

    Google Scholar 

  7. M. M. Dubinin, Zh. Fiz. Khim. 61, 1301 (1987).

    CAS  Google Scholar 

  8. Yu. B. Grunin, Doctoral (Chem.) Dissertation (Riga, 1989).

    Google Scholar 

  9. L. Yu. Grunin, Yu. B. Grunin, V. I. Talantsev, et al., Polym. Sci., Ser. A 57, 43 (2015).

    CAS  Article  Google Scholar 

  10. Yu. B. Grunin, L. Yu. Grunin, V. I. Talantcev, et al., Biophysics 60, 43 (2015).

    CAS  Article  Google Scholar 

  11. Y. Nishiyama, P. Langan, and H. Chanzy, J. Am. Chem. Soc. 124 (31), 9074 (2002).

    CAS  Article  Google Scholar 

  12. Y. Nishiyama, J. Sugiyama, H. Chanzy, et al., J. Am. Chem. Soc. 125, 14300 (2003).

    CAS  Article  Google Scholar 

  13. Y. Nishiyama, G. P. Johnson, A. D. French, et al., Biomacromol. 9, 3133 (2008).

    CAS  Article  Google Scholar 

  14. R. M. Brown, J. Polym. Sci., Ser. A: Polym. Chem. 42, 487 (2004).

    CAS  Article  Google Scholar 

  15. Y. B. Grunin, L. Y. Grunin, E. A. Nikolskaya, et al., Polym. Sci., Ser. A 54, 201 (2012).

    CAS  Article  Google Scholar 

  16. V. P. Nikolaev, A. A. Ageev, and Yu. G. Frolov, Tr. Mosk. Khim.-Tekhn. Inst. Mendeleeva, No. 101, 84 (1978).

    Google Scholar 

  17. www.nmr-design.com.

  18. Ya. I. Frenkel’, Kinetic Theory of Liquids (Nauka, Moscow, 1975) [in Russian].

    Google Scholar 

  19. V. I. Chizhik, Nuclear Magnetic Relaxation (St. Petersburg, 2004) [in Russian].

    Google Scholar 

  20. A. Abragam, The Principles of Nuclear Magnetism (Oxford Univ., Oxford, 1961).

    Google Scholar 

  21. Yu. B. Grunin, L. Yu. Grunin, and E. A. Nikol’skaya, Russ. J. Phys. Chem. A 81, 1165 (2007).

    CAS  Article  Google Scholar 

  22. Ya. I. Gerasimov, Course of Physical Chemistry (Khimiya, Moscow, 1973), Vols. 1, 2 [in Russian].

    Google Scholar 

  23. Yu. B. Grunin, L. Yu. Grunin, E. A. Nikolskaya, et al., Russ. J. Phys. Chem. A 87, 100 (2013).

    CAS  Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to L. Yu. Grunin.

Additional information

Original Russian Text © Yu.B. Grunin, L.Yu. Grunin, D.S. Masas, V.I. Talantsev, N.N. Sheveleva, 2016, published in Zhurnal Fizicheskoi Khimii, 2016, Vol. 90, No. 11, pp. 1696–1700.

Rights and permissions

Reprints and Permissions

About this article

Verify currency and authenticity via CrossMark

Cite this article

Grunin, Y.B., Grunin, L.Y., Masas, D.S. et al. Proton magnetic relaxation study of the thermodynamic characteristics of water adsorbed by cellulose fibers. Russ. J. Phys. Chem. 90, 2249–2253 (2016). https://doi.org/10.1134/S003602441611008X

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S003602441611008X

Keywords

  • cellulose–water system
  • adsorption isotherm
  • proton magnetic relaxation times
  • thermodynamic parameters