Abstract
The physicochemical (acidic-basic, adsorption, and electrophysical) surface properties of binary semiconductor analogs of CdBVI (CdTe, CdSe, and CdS), and (CdTe) x (CdSe)1–x , and (CdTe) x (CdS)1–x solid substitution solutions were studied using modern methods and equipment. The nature of the active centers and the mechanisms of acidic-basic, adsorption (involving СО), and electronic interactions, interrelated tendencies in variation of the surface properties under study, and their correlations with the known bulk physicochemical properties were elucidated; the property–composition diagrams were constructed, which were used to reveal the most active adsorbents suggested for use as materials for СО (carbon monoxide) microimpurity sensors.
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Original Russian Text © I.A. Kirovskaya, P.E. Nor, T.L. Bukashkina, E.V. Mironova, 2016, published in Zhurnal Fizicheskoi Khimii, 2016, Vol. 90, No. 3, pp. 331–338.
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Kirovskaya, I.A., Nor, P.E., Bukashkina, T.L. et al. Surface properties of semiconductor analogs of CdBVI and their solid substitution solutions. Russ. J. Phys. Chem. 90, 522–529 (2016). https://doi.org/10.1134/S0036024416030213
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DOI: https://doi.org/10.1134/S0036024416030213