Skip to main content
SpringerLink
Log in

Stability constants of Ni(II)- and Cu(II)-N-heterocycle complexes according to spectrophotometric data

  • Structure of Matter and Quantum Chemistry
  • Published:
Russian Journal of Physical Chemistry A Aims and scope Submit manuscript

Abstract

The interaction of Ni(II) and Cu(II) with ethyl 4-(4-hydroxyphenyl)-6-methyl-2-oxo-1,2,3,4-tetrahydropyrimidine- 5-carboxylate [Ligand 1], 4-(1H-benzimidazol-2-yl)phenol [Ligand 2], and 2-(3-phenylamino- 4,5-dihydro-1,2-oxazol-5-yl)phenol [Ligand 3] have been studied by spectrophotometric technique at 0.01 M ionic strength and 28°C in 70% dioxane—water mixture. The data obtained were used to estimate the stability constant of these ligands. Spectrophotometric investigation of Ni(II) and Cu(II) complexes with these ligands shows 1: 1 complex formation. The formation of complexes has been studied by Job’s variation method. The values of conditional stability constants of Cu(II) complexes are greater than the corresponding Ni(II) complexes. The greater value of stability constant of Cu(II) complexes may be due to the fact of more stable nature of Cu(II). The value of stability constant of Cu(II)—Ligand 2 complex is greater than that of Cu(II)–Ligand 1 and Cu(II)–Ligand 3. The same of Ni(II)–Ligand 3 complex is greater than that of Ni(II)–Ligand 1 and Ni(II)–Ligand 2.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. R. Rowland and C. E. Meloan, Anal. Chem. 42, 1261 (1970).

    Article  CAS  Google Scholar 

  2. B. G. Khobragade and M. L. Narwade, Acta Cienc. Ind. 9C, 32 (1983).

    Google Scholar 

  3. M. L. Narwade, S. W. Sathe, and M. M. Chincholkar, J. Ind. Chem. Soc. 62, 194 (1985).

    CAS  Google Scholar 

  4. M. L. Narwade, A. S. Wankhade, and B. G. Khobragade, J. Ind. Chem. Soc. 63, 360 (1986).

    Google Scholar 

  5. A. Atef and T. Ramdas, Asian J. Chem. 4, 457 (1992).

    Google Scholar 

  6. S. Sunita and V. K. Gupta, J. Ind. Chem. Soc. 64, 431 (1987).

    CAS  Google Scholar 

  7. A. Manimekalai and V. Thanikachalam, J. Ind. Chem. Soc. 68, 403 (1991).

    CAS  Google Scholar 

  8. J. D. Chavan and V. P. Joshi, Asian J. Chem. 4, 360 (1992).

    Google Scholar 

  9. P. D. Sawalakhe, PhD Thesis in Chemistry (Amravati Univ., Amaravati, 1992).

    Google Scholar 

  10. C. Bhargava and V. K. Tondon, Asian J. Chem. 4, 664 (1992).

    CAS  Google Scholar 

  11. P. D. Sawalakhe, in Proceedings of the Colloquium Spectroscopium International, Laughborough, UK, June 29, 1993.

    Google Scholar 

  12. P. B. Raghuwanshi and A. G. Doshi, Asian J. Chem. 8, 211 (1996).

    CAS  Google Scholar 

  13. P. J. Sondawale and M. L. Narwade, Orient. J. Chem. 13, 41 (1997).

    CAS  Google Scholar 

  14. A. R. Raut, S. N. Irfan Quazi, A. D. Khambre, S. A. Ikhe, and M. L. Narwade, Ultra Sci. 16, 203 (2004).

    CAS  Google Scholar 

  15. J. Dharmaraja, Th. Esakkidurai, P. Subbaraj, and S. Shobana, Spectrochim. Acta, Part A: Mol. Biomol. Spectrosc. 114, 607 (2013).

    Article  CAS  Google Scholar 

  16. V. M. Nurchi, G. Crisponi, M. Crespo-Alonso, J. I. Lachowicz, Z. Szewczuk, and G. J. S. Cooper, Dalton Trans. 42, 6161 (2013).

    Article  CAS  Google Scholar 

  17. I. L. Lere, M. G. Beyene, M. Chekol, and R. K. Upadhyay, Orient. J. Chem. 29, 1111 (2013).

    Article  CAS  Google Scholar 

  18. C. O. Kappe, Tetrahedron 49, 6937 (1993).

    Article  CAS  Google Scholar 

  19. K. S. Atwal, B. N. Swanson, S. E. Unger, S. Floyed Moreland, A. Hedberg, and B. C. O’Reilly, J. Med. Chem. 34, 806 (1991)

    Article  CAS  Google Scholar 

  20. C. O. Kappe, W. M. F. Fabian, and M. A. Semones, Tetrahedron 53, 2803 (1997)

    Article  CAS  Google Scholar 

  21. K. S. Atwal, G. C. Roonyak, B. C. O’Reilly, and A. Schwartz, J. Org. Chem. 54, 5898 (1989).

    Article  CAS  Google Scholar 

  22. N. Rao, R. Kumar, and Y. Srivastava, Rasayan J. Chem. 2, 716 (2009).

    CAS  Google Scholar 

  23. S. Dawane, G. Konda, M. Shaikh, S. Chobel, T. Khandare, T. Kamble, and B. Bhosale, Int. J. Pharm. Sci. Rev. Res. 1 (2), 09 (2010).

    Google Scholar 

  24. S. K. Gupta, S. S. Pancholi, M. K. Gupta, D. Agarwal, and M. P. Khinchi, J. Pharm. Sci. Res. 2, 228 (2010).

    CAS  Google Scholar 

  25. B. Vijaya, K. Rajeev, G. Varadaraj, and G. Gautham, Asian J. Res. Chem. 2, 162 (2009).

    Google Scholar 

  26. J. T. Leonard, O. S. Rajesh, L. Jeyaseeli, and K. Murugesh, Asian J. Chem. 19, 116 (2007).

    CAS  Google Scholar 

  27. Vogel's Textbook of Practical Organic Chemistry (Dorling Kindersley, 2006), p. 1162.

  28. Sonal Dilip Bajaj, O. A. Mahodaya, and P. V. Tekade, Pharmaceut. Chem. J. 48, 10 (2014).

    Google Scholar 

  29. K. Niknam and A. Fatehi Raviz, J. Iran. Chem. Soc. 4, 438 (2007).

    Article  CAS  Google Scholar 

  30. S. D. Bajaj, O. A. Mahodaya, and P. V. Tekade, Heterolett. 3, 219 (2013).

    CAS  Google Scholar 

  31. W. A. F. McBryde, Canad. J. Chem. 42, 1917 (1964).

    Article  CAS  Google Scholar 

  32. S. K. Banerjee, J. Inorg. Nucl. Chem. 32, 686 (1970).

    Article  Google Scholar 

  33. K. R. Gold and W. C. Vosburgh, J. Am. Chem. Soc. 64, 1630 (1942).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Jankidevi Bajaj College of Science, Jamnalal Bajaj Marg, Civil Lines, Wardha, India

    Samata Badhe, Pradip Tekade, Sonal Bajaj & Shrikant Thakare

Authors
  1. Samata Badhe
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Pradip Tekade
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Sonal Bajaj
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Shrikant Thakare
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Pradip Tekade.

Additional information

The article is published in the original.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Badhe, S., Tekade, P., Bajaj, S. et al. Stability constants of Ni(II)- and Cu(II)-N-heterocycle complexes according to spectrophotometric data. Russ. J. Phys. Chem. 89, 2254–2258 (2015). https://doi.org/10.1134/S0036024415120250

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036024415120250

Keywords

Search

Navigation