Abstract
The effect of the concentration of sodium di-(2-ethylhexyl) sulfosuccinate (AOT) on the volume and transport properties of the AOT/n-heptane/dimethylsulfoxide-water reverse micellar systems at different sulfoxide to water volume ratios, constant degree of AOT hydration R = 10, and temperatures of 298.15–313.15 K was studied by densimetry and viscosimetry. The apparent volumes of the polar phases and the volume fractions of micelles were calculated using the densities of these systems. In the presence of dimethylsulfoxide, an increase in its concentration led to an increase in the apparent volume of the polar phase; an increase in the AOT concentration at increased viscosity of the system led to a decrease in the apparent volume of the micellar nucleus.
Similar content being viewed by others
References
K. I. Evstratova, N. A. Kupina, and E. E. Malakhov, Physical and Colloid Chemistry (Vyssh. Shkola, Moscow, 1990) [in Russian].
T. Hirai, Y. Nomura, and I. Komasawa, J. Nanopart. Res. 5, 61 (2003).
J. Eastoe, M. J. Hollamby, and L. Hudson, Adv. Colloid Interfac. 128–130, 5 (2006).
I. Beletskaya and V. Tyurin, Molecules 15, 4792 (2010).
A. N. Eremin, G. K. Zhavnerko, and V. E. Agabekov, Colloid. J. 74, 445 (2012).
B. Orlich and R. Schomacker, Adv. Biochem. Eng. Biotechnol. 75, 185 (2002).
R. Biswas and S. K. Pal, Chem. Phys. Lett. 387, 221 (2004).
N. M. Correa, J. J. Silber, R. E. Riter, and N. E. Levinger, Chem. Rev. 112, 4569 (2012).
R. D. Falcone, N. M. Correa, and J. J. Silber, Phys. Chem. Chem. Phys. 11, 11096 (2009).
R. N. Khamidullin, Yu. F. Zuev, and N. N. Vylegzhanina, Strukt. Dinam. Mol. Sistem, No. 10, 71 (2003).
H. Walderhaug and E. Johannessen, J. Solution Chem. 35, 979 (2006).
F. Moyano, E. Setien, J. J. Silber, and N. M. Correa, Langmuir 29, 8245 (2013).
S. A. Markarian, J. D. Grigoryan, and H. R. Sargsyan, Int. J. Pharm. 353, 52 (2008).
V. I. Kartsev, S. I. Shtykov, A. V. Sineva, V. V. Tsepulin, and L. S. Shtykova, Colloid. J. 74, 394 (2003).
A. D. Aprano, I. D. Donato, M. Goffredi, and V. T. Liveri, J. Solution Chem. 21, 323 (1992).
A. R. Sargsyan, G. A. Shahinyan, and Sh. A. Markaryan, Russ. J. Phys. Chem. A 88, 858 (2014).
S. W. Jacob and R. Herschler, Cryobiology 23, 14 (1986).
Z. W. Yu and P. I. Quinn, Biosci. Rep. 14, 259 (1994).
M. A. Saleh, S. Akhtar, M. S. Ahmed, and M. H. Uddin, Phys. Chem. Liq 40, 621 (2002).
M. Rhodes, Introduction to Particle Technology, 2nd ed. (Wiley, 2008).
O. Smidsrod and S. T. Moe, Biopolymer Chemistry (Tapir Academic Press, 2008).
A. Ruggirello and V. T. Liveri, J. Chem. Phys. 208, 187 (2003).
M. Goffredi and V. T. Liveri, Emuls. Microemuls. 112, 109 (1999).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © Sh.A. Markaryan, A.R. Sarkisyan, G.A. Shaginyan, 2015, published in Zhurnal Fizicheskoi Khimii, 2015, Vol. 89, No. 10, pp. 1606–1611.
Rights and permissions
About this article
Cite this article
Markaryan, S.A., Sarkisyan, A.R. & Shaginyan, G.A. Effect of the dioctyl sodium sulfosuccinate (AOT) concentration on the properties of the AOT-n-heptane-DMSO-water micellar system. Russ. J. Phys. Chem. 89, 1808–1813 (2015). https://doi.org/10.1134/S003602441509023X
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S003602441509023X