Abstract
The effect the concentration of sodium hydroxide has on the catalytic activity of skeletal nickel in reactions of the liquid-phase hydrogenation of sodium maleate in ternary methanol-water-sodium hydroxide solutions with a methanol content of 0.11 mole fractions and different concentrations of sodium hydroxide is studied. The key role of the solvent during changes in the activity of skeletal nickel in the hydrogenation reaction of sodium maleate is assumed, based on data on the redistribution of individual forms of adsorbed hydrogen.
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Original Russian Text © M.V. Lukin, A.V. Afineevskii, 2015, published in Zhurnal Fizicheskoi Khimii, 2015, Vol. 89, No. 7, pp. 1089–1094.
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Lukin, M.V., Afineevskii, A.V. Effect of additions of sodium hydroxide on the catalytic activity of partially deactivated skeletal nickel in reactions of the liquid-phase hydrogenation of sodium maleate in aqueous-organic media. Russ. J. Phys. Chem. 89, 1173–1177 (2015). https://doi.org/10.1134/S0036024415070237
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DOI: https://doi.org/10.1134/S0036024415070237