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Quenchers and inhibitors of chemiluminescence in the reduction reactions of Mn3+

  • Photochemistry and Magnetochemistry
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Abstract

The effect of NaF and CH3CN on the chemiluminescent reactions of Mn(III) reduction in solutions of sulfuric acid is studied. It is established that NaF is an inhibitor of these reactions, and the quenching of chemiluminescence under the effect of NaF is nominal. Acetonitrile does not affect the kinetics of reactions under similar conditions and acts as a specific quencher of the chemiexcited emitter. The Stern-Volmer quenching constant is 52 ± 11 M−1.

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Authors and Affiliations

  1. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, Moscow, 119334, Russia

    Yu. B. Tsaplev, R. F. Vasil’ev & A. V. Trofimov

Authors
  1. Yu. B. Tsaplev
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  2. R. F. Vasil’ev
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  3. A. V. Trofimov
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Correspondence to Yu. B. Tsaplev.

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Original Russian Text © Yu.B. Tsaplev, R.F. Vasil’ev, A.V. Trofimov, 2015, published in Zhurnal Fizicheskoi Khimii, 2015, Vol. 89, No. 6, pp. 1038–1042.

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Tsaplev, Y.B., Vasil’ev, R.F. & Trofimov, A.V. Quenchers and inhibitors of chemiluminescence in the reduction reactions of Mn3+ . Russ. J. Phys. Chem. 89, 1103–1107 (2015). https://doi.org/10.1134/S0036024415060308

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  • DOI: https://doi.org/10.1134/S0036024415060308

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