Skip to main content
SpringerLink
Log in

Separation of (+)-catechin and quercetin on mesoporous MCM-41 composites: Dynamics of the sorption of flavonoids

  • Physical Chemistry of Separation Processes: Chromatography
  • Published:
Russian Journal of Physical Chemistry A Aims and scope Submit manuscript

Abstract

An analysis of conditions for chromatographic separation of quercetin and (+)-catechin based on experimental data and using the equations of an asymptotic model of sorption dynamics for substances characterized by convex isotherms of sorption is presented. The effects of the equilibrium (distribution coefficient) and kinetic (diffusion coefficient) factors on the dynamics of the sorption of flavonoids by ordered mesoporous material of the MCM-41 type and its composites with grafted organosilane groups is considered. The effects of kinetic and equilibrium parameters on the broadening of adsorption fronts is demonstrated with allowance for the inner and outer diffusion limitations of the sorption process.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. G. V. Samsonov, E. B. Trostyanskaya, and G. E. El’kin, Ion Exchange: Adsorption of Organic Substances (Nauka, Leningrad, 1969) [in Russian].

    Google Scholar 

  2. V. V. Belakhov and N. N. Momot, Russ. J. Appl. Chem. 83, 1683 (2010).

    Article  CAS  Google Scholar 

  3. V. V. Rachinskii, An Introduction to the General Theory of Sorption and Chromatography Dynamics (Nauka, Moscow, 1964) [in Russian].

    Google Scholar 

  4. E. V. Venetsianov and R. N. Rubenshtein, Dynamics of Sorption from Liquid Media (Nauka, Moscow, 1983) [in Russian].

    Google Scholar 

  5. E. K. Zolotareva and V. K. Opanasenko, in Properties of Flavonoids and Their Function in Metabolism of the Plant Cell, Collection of Articles (Pushchino, 1986), pp. 22–38 [in Russian].

    Google Scholar 

  6. A. I. Volzhinskii and V. A. Konstantinov, Ionites Regeneration (Khimiya, Leningrad, 1990) [in Russian].

    Google Scholar 

  7. J. S. Beck, J. C. Vartuli, W. J. Roth, et al., J. Am. Chem. Soc. 114, 10834 (1992).

    Article  CAS  Google Scholar 

  8. C. T. Kresge, M. E. Leonowicz, W. J. Roth, et al., Nature 359, 710 (1992).

    Article  CAS  Google Scholar 

  9. P. J. Branton, P. G. Hall, and K. S. W. Sing, Adsorption 1, 77 (1994).

    Article  Google Scholar 

  10. K. Ariga, A. Vinu, J. P. Hill, and T. Mori, Coord. Chem. Rev. 251, 2562 (2007).

    Article  CAS  Google Scholar 

  11. M. Vallet-Regi, Chem. Eur. J. 12, 5934 (2006).

    Article  CAS  Google Scholar 

  12. G. Chandrasekar, A. Vinu, V. Murugesan, and M. Hartmann, Studies Surf. Sci. Catal. 158, 1169 (2005).

    Article  Google Scholar 

  13. S. I. Karpov, N. A. Belanova, E. O. Korabel’nikova, et al., Russ. J. Phys. Chem. A 89, 880 (2015).

    Article  Google Scholar 

  14. X. S. Zhao, G. Q. Lu, A. K. Whittaker, et al., J. Phys. Chem. B 101, 6525 (1997).

    Article  CAS  Google Scholar 

  15. N. A. Belanova, S. I. Karpov, I. V. Nedosekina, et al., Sorbtsion. Khromatogr. Protsessy 12, 240 (2012).

    Google Scholar 

  16. N. A. Belanova, S. I. Karpov, V. F. Selemenev, and E. O. Chepeleva, Zavod. Lab., Diagn. Mater. 77(12), 21 (2011).

    CAS  Google Scholar 

  17. N. A. Udalova, S. I. Karpov, V. F. Selemenev, and I. A. Sharmar, Russ. J. Phys. Chem. A 83, 1006 (2009).

    Article  CAS  Google Scholar 

  18. E. O. Korabel’nikova, N. A. Belanova, S. I. Karpov, et al., in Proceedings of the 2nd All-Russia Symposium with International Participation on Kinetics and Dynamics of Exchange Processes (2013), p. 144.

    Google Scholar 

  19. V. A. Kuz’minykh and G. A. Chikin, Teor. Prakt. Sorbtsion. Protsessov, No. 16, 3 (1983).

    Google Scholar 

  20. Yu. A. Kokotov, Ion-Exchangers and Ion Exchange (Khimiya, Leningrad, 1980) [in Russian].

    Google Scholar 

  21. L. K. Shataeva, N. N. Kuznetsova, and G. E. El’kin, in Carboxyl Cationites in Biology, Ed. by G. V. Samsonov (Nauka, Leningrad, 1979), p. 286 [in Russian].

  22. V. A. Kuz’minykh and V. P. Meleshko, Zh. Fiz. Khim. 54, 973 (1980).

    Google Scholar 

  23. V. A. Kuz’minykh, V. P. Meleshko, and Yu. V. Golitsyn, Zh. Fiz. Khim. 54, 1802 (1980).

    Google Scholar 

  24. V. A. Kuz’minykh, G. A. Chikin, and V. F. Selemenev, in Proceedings of the 8th Regional Conference on Problems of Chemistry and Chemical Technology (Voronezh, St. Petersburg, 2000), p. 123.

    Google Scholar 

  25. V. A. Kuz’minykh, G. A. Chikin, and Yu. V. Golitsyn, Zh. Fiz. Khim. 58, 2778 (1984).

    Google Scholar 

  26. S. I. Karpov, F. Roessner, V. F. Selemenev, N. A. Belanova, and O. O. Krizhanovskaya, Russ. J. Phys. Chem. A 87, 1888 (2013).

    Article  CAS  Google Scholar 

  27. S. I. Karpov, F. Roessner, V. F. Selemenev, et al., Sorbtsion. Khromatogr. Protsessy, No. 3, 273 (2013).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Faculty of Chemistry, Voronezh State University, Voronezh, 349006, Russia

    S. I. Karpov & E. O. Korabel’nikova

Authors
  1. S. I. Karpov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. O. Korabel’nikova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to S. I. Karpov.

Additional information

Original Russian Text © S.I. Karpov, E.O. Korabel’nikova, 2015, published in Zhurnal Fizicheskoi Khimii, 2015, Vol. 89, No. 6, pp. 1030–1037.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Karpov, S.I., Korabel’nikova, E.O. Separation of (+)-catechin and quercetin on mesoporous MCM-41 composites: Dynamics of the sorption of flavonoids. Russ. J. Phys. Chem. 89, 1096–1102 (2015). https://doi.org/10.1134/S0036024415060151

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036024415060151

Keywords

Search

Navigation