Abstract
The enthalpies of dissolution of n-hexane, n-octane, and n-decane are determined thermochemically under standard conditions to describe nonspecific solvation in a mixed solvent of methanol-formamide. Experimental data are matched with the values obtained using model calculations. It is found that the differences between the experimental and calculated enthalpies of dissolution in the region with a high content of formamide could be due to the preferable solvation of n-alkanes by methanol.
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References
V. P. Belousov and A. G. Morachevskii, Heats of Mixing of Liquids (Khimiya, Leningrad, 1970) [in Russian].
V. P. Belousov, A. G. Morachevskii, and M. Yu. Pakov, Thermal Properties of Nonelectrolyte Solutions (Khimiya, Leningrad, 1981) [in Russian].
V. N. Afanas’ev, L. S. Efremova, and T. V. Volkova, Physicochemical Properties of Binary Solvents (Ivanovo, 1988) [in Russian].
G. A. Krestov, V. N. Afanas’ev, and L. S. Efremova, Physicochemical Properties of Binary Solvents (Khimiya, Leningrad, 1988) [in Russian].
T. E. Burchfield and G. L. Bertrand, J. Solution Chem. 4, 205 (1975).
V. P. Korolev, D. V. Batov, and O. A. Antonova, Zh. Obshch. Khim. 63, 2200 (1993).
M. V. Kulikov, M. Yu. Kropotova, and V. P. Korolev, Russ. J. Gen. Chem. 66, 1388 (1996).
M. V. Kulikov, M. Yu. Kropotova, and V. P. Korolev, Russ. J. Gen. Chem. 67, 1840 (1997).
V. N. Vandyshev, A. L. Serebryakova, and V. I. Savel’ev, in Proceedings of the 6th International Conference on Problems of Solvation and Complex Formation in Solutions (Ivanovo, 1995), p. K–11.
V. P. Korolev, N. L. Smirnova, O. A. Antonova, and A. V. Kustov, Russ. J. Gen. Chem. 78, 2013 (2008).
H. A. Zarei and H. Iloukhani, Thermochim. Acta 405, 123 (2003).
A. C. Gómez Marigliano, and H. N. Sólimo, J. Chem. Eng. Data 47, 796 (2002).
A. V. Kustov, A. A. Emel’yanov, A. F. Syshchenko, M. A. Krest’yaninov, N. I. Zheleznyak, and V. P. Korolev, Russ. J. Phys. Chem. A 80, 1532 (2006).
D. Berling and G. Olofsson, J. Solution Chem. 23, 911 (1994).
D. V. Batov and V. P. Korolev, Zh. Obshch. Khim. 62, 2429 (1992).
G. A. Krestov, V. P. Korolev, and D. V. Batov, Dokl. Ross. Akad. Nauk 326, 851 (1992).
G. A. Krestov, V. P. Korolev, and D. V. Batov, Dokl. Ross. Akad. Nauk 331, 693 (1993).
V. P. Korolev and D. V. Batov, Zh. Obshch. Khim. 64, 576 (1994).
D. V. Batov, Russ. J. Gen. Chem. 68, 184 (1998).
D. V. Batov, Extended Abstract of Doctoral Dissertation in Chemistry (Ivanovo, 2002).
W. J. M. Heuvelsland, C. de Visser, and G. Somsen, J. Chem. Soc., Faraday Trans. I 77, 1191 (1981).
A. V. Kustov, N. L. Smirnova, O. A. Antonova, and V. P. Korolev, Russ. J. Phys. Chem. A 82, 233 (2008).
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Original Russian Text © D.V. Batov, A.V. Kustov, O.A. Antonova, N.L. Smirnova, 2015, published in Zhurnal Fizicheskoi Khimii, 2015, Vol. 89, No. 6, pp. 952–956.
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Batov, D.V., Kustov, A.V., Antonova, O.A. et al. Enthalpies of dissolution of n-alkanes in a mixture of methanol-formamide. Russ. J. Phys. Chem. 89, 993–997 (2015). https://doi.org/10.1134/S0036024415060060
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DOI: https://doi.org/10.1134/S0036024415060060