Abstract
The combustion enthalpy of diosgenin was determined by oxygen-bomb calorimetry. The standard mole combustion enthalpy and the standard mole formation enthalpy have been calculated to be −16098.68 and −528.52 kJ mol−1, respectively. Fusion enthalpy and melting temperature for diosgenin were also measured to be −34.43 kJ mol−1 and 212.33°C, respectively, according to differential scanning calorimetry (DSC) data. These studies can provide useful thermodynamic data for this compound.
References
Weisheng Tian, Qihai Xu, Ling Chen, et al., Sci. China Ser. B: Chem. 47, 142 (2004).
Heping Li, Hongmin Liu, Wenzhong Ge, et al., Steroids 70, 970 (2005).
Feixiong Chen, Mingrui Zhao, Chuochuo Liu, et al., J. Chem. Thermodyn. 50, 1 (2012).
Feixiong Chen, Mingrui Zhao, Baozeng Ren, et al., J. Chem. Thermodyn. 47, 341 (2012).
Feixiong Chen, Fu Li, Feng Lu, et al., Russ. J. Phys. Chem. A 87, 1611 (2013)
Xin Yu, Cairong Zhou, Xuewei Han, et al., J. Therm. Anal. Calorim. 111, 943 (2013).
Xuewei Han, Cairong Zhou, and Xiaohua Shi, J. Therm. Anal. Calorim. 109, 441 (2012).
Zh. Wang and Y. Zhou, Physics Chemistry, 4th ed. (High Edu Press, China, 2001).
H.-Ch. Li and B. Fu, Handbook of Chemurgy (Chem. Industry Press, China, 2006).
G. W. Gokel, Dean’s Handbook of Organic Chemistry, 2nd ed. (McGraw-Hill Education (Asia) Co., Chemical Industry Press, Beijing, 2006).
J. L. de la Fuente, M. Ruiz-Bermejo, C. Menor-Salvan, et al., Polym. Degrad. Stabil. 96, 943–948 (2011).
Yu. Chou, T.-F. Hsieh, Yu. Hsieh, et al., J. Therm. Anal. Calorim. 102, 641 (2010).
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Zhao, MR., Wang, HJ., Wang, SY. et al. Thermodynamic properties of diosgenin determined by oxygen-bomb calorimetry and DSC. Russ. J. Phys. Chem. 88, 2280–2282 (2014). https://doi.org/10.1134/S003602441412022X
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DOI: https://doi.org/10.1134/S003602441412022X