Abstract
The crystal solvates in C60-CCl4 and C70-CCl4 systems obtained by crystallization from CCl4 solution at room temperature were studied by IR Fourier spectroscopy and X-ray diffraction. The C70 · (CCl4) n crystal solvate was obtained and studied for the first time; its hexagonal crystal lattice has unit cell parameters a = 10.658 ± 0.001 Å and c = 10.811 ± 0.002 Å. The temperature ranges of its destruction were determined.
Similar content being viewed by others
References
V. V. Aksenova, R. M. Nikonova, V. I. Lad’yanov, et al., Russ. J. Phys. Chem. A 87, 1002 (2013).
A. K. Gangopadhyay, J. S. Schilling, M. de Leo, et al., Solid State Commun. 96, 597 (1995).
R. Ceolin, V. Agafonov, D. Andre, et al., Chem. Phys. Lett. 208, 259 (1993).
Y. Nagano and T. Nakamura, Chem. Phys. Lett. 252, 362 (1996).
M. Barrio, D. O. Lopez, J. Ll. Tamarit, et al., Chem. Phys. Lett. 260, 78 (1996).
Y. Nagano and T. Nakamura, Chem. Phys. Lett. 265, 358 (1997).
D. V. Konarev, V. N. Semkin, R. N. Lyubovskaya, et al., J. Mol. Struct. 450, 11 (1998).
V. N. Semkin, N. V. Drichko, A. V. Talysin, et al., Synth. Met. 93, 207 (1998).
V. I. Lad’yanov, V. V. Aksenova, and R. M. Nikonova, Russ. J. Phys. Chem. A 84, 1548 (2010).
V. V. Aksenova, R. M. Nikonova, V. I. Lad’yanov, et al., Russ. J. Phys. Chem. A 87, 1749 (2013).
L. A. Solovyov, N. V. Bulina, and G. N. Churilov, Russ. Chem. Bull. Int. Ed. 50, 78 (2001).
V. V. Aksenova, R. M. Nikonova, V. I. Lad’yanov, et al., Russ. J. Phys. Chem. A 87, 1194 (2013).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © V.V. Aksenova, R.M. Nikonova, V.L. Lad’yanov, V.V. Mukhgalin, 2014, published in Zhurnal Fizicheskoi Khimii, 2014, Vol. 88, No. 10, pp. 1535–1541.
Rights and permissions
About this article
Cite this article
Aksenova, V.V., Nikonova, R.M., Lad’yanov, V.L. et al. Thermostimulated structural changes in C60-CCl4 and C70-CCl4 crystal solvates. Russ. J. Phys. Chem. 88, 1726–1731 (2014). https://doi.org/10.1134/S0036024414100021
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036024414100021