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Mobility of molecules of liquid diols in the temperature range of 303–318 K

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Abstract

The self-diffusion coefficients of diols (ethylene glycol (EG), 1,2- and 1,3-propanediols (PD), and 1,4-butanediol (BD)) are measured using the spin echo approach on protons in the temperature range of 303–318 K. The activation energies of self-diffusion are calculated and compared to the activation energies for viscous flow and dipole relaxation in these systems. A conclusion is reached as to the correlation of rotational and translational movements in liquid diols, due to the presence of a spatial network of hydrogen bonds in these solvents.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russia

    M. N. Rodnikova & I. A. Solonina

  2. Kazan National Research Technological University, Kazan, 420015, Russia

    Z. Sh. Idiyatullin

Authors
  1. M. N. Rodnikova
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  2. Z. Sh. Idiyatullin
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  3. I. A. Solonina
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Correspondence to M. N. Rodnikova.

Additional information

Original Russian Text © M.N. Rodnikova, Z.Sh. Idiyatullin, I.A. Solonina, 2014, published in Zhurnal Fizicheskoi Khimii, 2014, Vol. 88, Nos. 7–8, pp. 1270–1272.

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Rodnikova, M.N., Idiyatullin, Z.S. & Solonina, I.A. Mobility of molecules of liquid diols in the temperature range of 303–318 K. Russ. J. Phys. Chem. 88, 1442–1444 (2014). https://doi.org/10.1134/S003602441408024X

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  • DOI: https://doi.org/10.1134/S003602441408024X

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