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Synthesis, crystal structure, and photoluminescence of a zinc metalloporphyrin

  • Photochemistry and Magnetochemistry
  • Published:
Russian Journal of Physical Chemistry A Aims and scope Submit manuscript

Abstract

A zinc metalloporphyrin, ZnTCPP(acetone) (1) (TCPP = meso-tetra(4-carboxyphenyl)porphyrin), has been prepared via a solvothermal reaction and structurally characterized by single-crystal X-ray diffraction. Compound 1 features an isolated structure with a planar macrocycle and an embedded zinc ion binded to four pyrrole nitrogen atoms and one acetone oxygen atom. Photoluminescent investigation reveals that compound 1 displays an intensive emission in the red region.

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Authors and Affiliations

  1. Institute of Applied Chemistry, School of Chemistry and Chemical Engineering, Jiangxi Province Key Laboratory of Coordination Chemistry, Jinggangshan University, 343009, Ji’an, Jiangxi, China

    Wen-Tong Chen, Xiu-Guang Yi & Zhi-Gang Luo

  2. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, China

    Wen-Tong Chen, Hong-Ru Fu & Juan Liu

Authors
  1. Wen-Tong Chen
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  2. Xiu-Guang Yi
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  3. Zhi-Gang Luo
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  4. Hong-Ru Fu
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  5. Juan Liu
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Correspondence to Wen-Tong Chen.

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Chen, WT., Yi, XG., Luo, ZG. et al. Synthesis, crystal structure, and photoluminescence of a zinc metalloporphyrin. Russ. J. Phys. Chem. 88, 1228–1231 (2014). https://doi.org/10.1134/S0036024414070309

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  • DOI: https://doi.org/10.1134/S0036024414070309

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