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One-pot, one-step, catalytic synthesis of 2,5-diformylfuran from fructose

  • Chemical Kinetics and Catalysis
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Russian Journal of Physical Chemistry A Aims and scope Submit manuscript

Abstract

MIL-101, a chromium-based metal-organic framework, is known for its very large pore size, large surface area and good stability. However, application of this material in catalysis is still limited. In this paper, a simple and practical catalytic method for the preparation 2,5-diformylfuran (DFF) directly from fructose was investigated. 5% Pd-V(3: 2)@MIL-101 was evaluated as a potential and effective catalyst for the direct oxidation of fructose. The amount of the catalyst, reaction time and temperature had a large effect on the reaction. At the optimized reaction conditions, when the reaction was conducted at 140°C for 600 min, 1 atm oxygen pressure, the yield of DFF reached 34%, fructose conversion was up to 100%. In our system, the main side products were 5-formyl-2-furancarboxylic acid (FFCA) and 2,5-furandicarboxylic acid (FDCA), which are the products of deep oxidation of DFF. This simple and effective catalytic system may be valuable to facilitate energy-efficient conversion of fructose into biofuels and platform chemicals.

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Authors and Affiliations

  1. Shandong Provincial Key Laboratory of Fine Chemicals, Qilu University of Technology, Jinan, 250353, P.R. China

    Furong Tao, Yuezhi Cui, Pengfei Yang & Yinghua Gong

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  1. Furong Tao
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  2. Yuezhi Cui
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  3. Pengfei Yang
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  4. Yinghua Gong
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Correspondence to Furong Tao.

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Tao, F., Cui, Y., Yang, P. et al. One-pot, one-step, catalytic synthesis of 2,5-diformylfuran from fructose. Russ. J. Phys. Chem. 88, 1091–1096 (2014). https://doi.org/10.1134/S0036024414070152

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  • DOI: https://doi.org/10.1134/S0036024414070152

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