Skip to main content

Apparent molar and partial molar volumes of aqueous ceric ammonium nitrate solutions at 20, 25, 30, and 35°C

Russian Journal of Physical Chemistry A volume 88, pages 1124–1128 (2014)Cite this article

Abstract

Present paper reports the measured densities (ρ) and refractive indices (n D) of aqueous solutions of ceric ammonium nitrate (CAN) at 20, 25, 30, and 35°C in different concentrations of solution. Apparent molar volumes (φv) have been calculated from the density data at different temperatures and fitted to Massons relation to get limiting partial molar volumes (ϕ 0v ) of CAN. Refractive index data were fitted to linear dependence over concentration of solutions and values of constant K and n 0D for different temperatures were evaluated. Specific refractions (R D) of solutions were calculated from the refractive index and density data. Concentration and temperature effects on experimental and derived properties have been discussed in terms of structural interactions.

This is a preview of subscription content, access via your institution.

Access options

Buy single article

Instant access to the full article PDF.

USD 39.95

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

References

  1. B. Sinha, V. K. Dakua, and M. N. Roy, J. Chem. Eng. Data 52, 1768 (2007).

    Article  CAS  Google Scholar 

  2. M. J. Iqbal and M. A. Chaudhry, J. Chem. Thermodyn. 41, 221 (2009).

    Article  CAS  Google Scholar 

  3. S. L. Clegg and A. S. Wexler, J. Phys. Chem. A 115, 3393 (2011).

    Article  CAS  Google Scholar 

  4. A. Pal and N. Chauhan, J. Solut. Chem. 39, 1636 (2010).

    Article  CAS  Google Scholar 

  5. N. Calvar, B. González, A. Domínguez and J. Tojo, J. Solut. Chem. 35, 1217 (2006).

    Article  CAS  Google Scholar 

  6. R. Zarrougui, M. Dhahbi, and D. Lemordant, Ionics 17, 343 (2011).

    Article  CAS  Google Scholar 

  7. D. C. Kabiraz, T. K. Biswas, and M. E. Huque, Monatsh Chem. 141, 1063 (2010).

    Article  CAS  Google Scholar 

  8. L. H. Blanco and E. F. Vargas, J. Solut. Chem. 35, 21 (2006).

    Article  CAS  Google Scholar 

  9. C. Klofutar, J. Horvat, and D. Rudan-Tasic, Acta Chem. Slov. 53, 274 (2006).

    CAS  Google Scholar 

  10. D. C. Kabiraz, T. K. Biswas, and M. E. Huque, Monatsh Chem. 141, 1063 (2010).

    Article  CAS  Google Scholar 

  11. H. R. Corti and J. M. Simonson, J. Solut. Chem. 35, 1057 (2006).

    Article  CAS  Google Scholar 

  12. S. J. Kharat, J. Mol. Liq. 140, 10 (2008).

    Article  CAS  Google Scholar 

  13. S. D. Deosarkar, A. L. Puyad, P. S. Kattekar, and T. M. Kalyankar, Russ. J. Phys. Chem. A 87, 524 (2013).

    Article  CAS  Google Scholar 

  14. S. D. Deosarkar, Russ. J. Phys. Chem. A 86, 1507 (2012).

    Article  CAS  Google Scholar 

  15. S. D. Deosarkar, A. L. Puyad, and T. M Kalyankar, Russ. J. Phys. Chem. A 86, 775 (2012).

    Article  CAS  Google Scholar 

  16. W. M. B. M. Yunus, and A. B. A. Rahman, Appl. Opt. 27, 334 (1998).

    Google Scholar 

  17. M. N. Roy, A. Banerjee, and P. K. Roy, Int. J. Thermophys. 30, 515 (2009).

    Article  CAS  Google Scholar 

  18. D. R. Delgado, A. F. Jimenez-Kairuz, R. H. Manzo, E. F. Vargas, and F. Martinez, Rev. Colomb. Cienc. Quim. Farm. 39, 57 (2010).

    Google Scholar 

  19. I. M. Abdulagatov and N. D. Azizov, J. Solut. Chem. 34, 645 (2005).

    Article  CAS  Google Scholar 

  20. F. Koohyar, A. A. Rostami, M. J. Chaich, and F. Kiani, J. Solut. Chem. 40, 1361 (2011).

    Article  CAS  Google Scholar 

  21. D. O. Masson, Philos. Mag. 8, 218 (1929).

    CAS  Google Scholar 

  22. D. Choudhary and A. Aswar, J. Therm. Anal. Calorim. 107, 21 (2012).

    Article  CAS  Google Scholar 

  23. P. S. Nikam, R. P. Shewale, A. B. Sawant, and M. Hasan, J. Chem. Eng. Data 50, 487 (2005).

    Article  CAS  Google Scholar 

  24. M. N. Roy, A. Banerjee, and P. K. Roy, Int. J. Thermophys. 30, 515 (2009).

    Article  CAS  Google Scholar 

  25. T. Imai, Condens. Matter Phys. 10, 343 (2007).

    Article  Google Scholar 

  26. M. N. Roy, V. K. Dakua, and B. Sinha, Int. J. Thermophys. 28, 1275 (2007).

    Article  CAS  Google Scholar 

  27. M. L. Parmar, R. K. Awasthi, and M. K. Guleria, J. Chem. Sci. 116, 33 (2004).

    Article  CAS  Google Scholar 

  28. D. Rudan-Tasic and C. Klofutar, Monatsh Chem. 129, 1245 (1998).

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. School of Chemical Sciences, Swami Ramanand Teerth Marathwada University, Nanded, 431 606, MS, India

    S. D. Deosarkar, S. G. Wanale & M. P. Shelke

Authors
  1. S. D. Deosarkar
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. G. Wanale
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. P. Shelke
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to S. D. Deosarkar.

Additional information

The article is published in the original.

Rights and permissions

Reprints and Permissions

About this article

Verify currency and authenticity via CrossMark

Cite this article

Deosarkar, S.D., Wanale, S.G. & Shelke, M.P. Apparent molar and partial molar volumes of aqueous ceric ammonium nitrate solutions at 20, 25, 30, and 35°C. Russ. J. Phys. Chem. 88, 1124–1128 (2014). https://doi.org/10.1134/S0036024414070127

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036024414070127

Keywords

  • CAN
  • density
  • refractive index
  • apparent molal volumes
  • partial molar volume