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Equilibrium liquid-vapor diagrams of ternary systems with three azeotropes

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Abstract

Forty-nine classes involving 222 types of ternary liquid-vapor systems with three azeotropes are revealed. The place of three-azeotrope systems in the thermodynamic classification of binary solutions is determined. Examples of phase portraits of liquid-vapor equilibrium with three azeotropes in various elements of the concentration triangle (binary components, internal region, and binary components and the internal region) are presented.

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References

  1. L. A. Serafimov, Russ. J. Phys. Chem. A 76, 1211 (2002).

    Google Scholar 

  2. W. Swietoslawski, Azeotropy and Polyazeotropy (Pergamon Press, Oxford, London, New York, Paris 1963; Khimiya, Moscow, 1968).

    Google Scholar 

  3. L. A. Serafimov and A. K. Frolkova, Theor. Found. Chem. Eng. 31, 159 (1997).

    CAS  Google Scholar 

  4. A. K. Frolkova, Separation of Azeotropic Mixtures (Vlados, Moscow, 2010) [in Russian].

    Google Scholar 

  5. L. A. Serafimov, A. K. Frolkova, and T. V. Chelyuskina, Theor. Found. Chem. Eng. 43, 889 (2009).

    Article  CAS  Google Scholar 

  6. T. V. Chelyuskina, A. K. Frolkova, and L. A. Serafimov, Vestn. Kazan. Tekhnol. Univ., No. 2, 63 (2010).

    Google Scholar 

  7. A. K. Frolkova, Doctoral Dissertation in Technical Science (Moscow, 2000).

  8. L. A. Nisel’son and G. V. Astakhova, Dokl. Akad. Nauk SSSR 192, 1311 (1970).

    Google Scholar 

  9. L. A. Serafimov, A. V. Frolkova, and V. V. Illarionov, Vestn. MITKhT 5(3), 10 (2010).

    Google Scholar 

  10. L. A. Serafimov, A. K. Frolkova, and V. M. Raeva, Theor. Found. Chem. Eng. 30, 557 (1996).

    CAS  Google Scholar 

  11. V. M. Raeva and A. K. Frolkova, Vestn. MITKhT 4(4), 31 (2009).

    Google Scholar 

  12. A. K. Frolkova, V. M. Raeva, and L. A. Serafimov, Classification of Binary Liquid Solutions in Terms of Excess Thermodynamical Functions (MITKhT, Moscow, 2010) [in Russian].

    Google Scholar 

  13. L. V. Baburina and N. S. Maklashina, Russ. J. Phys. Chem. A 71, 555 (1997).

    Google Scholar 

  14. L. A. Serafimov, Zh. Fiz. Khim. 44, 1021 (1970).

    CAS  Google Scholar 

  15. L. A. Serafimov, Theor. Found. Chem. Eng. 35, 237 (2001).

    Article  CAS  Google Scholar 

  16. L. A. Serafimov and T. V. Chelyuskina, Russ. J. Phys. Chem. A 85, 767 (2011).

    Article  CAS  Google Scholar 

  17. J. Guckenheimer and F. Holmes, Nonlinear Oscillations, Dynamical Systems and Bifurcations of Vector Fields (Springer, Berlin, Heidelberg, New York, 1983; Izhevsk, Moscow, 2002).

    Google Scholar 

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Correspondence to V. M. Raeva.

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Original Russian Text © V.M. Raeva, L.A. Serafimov, V.N. Stepanov, 2013, published in Zhurnal Fizicheskoi Khimii, 2013, Vol. 87, No. 7, pp. 1177–1185.

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Raeva, V.M., Serafimov, L.A. & Stepanov, V.N. Equilibrium liquid-vapor diagrams of ternary systems with three azeotropes. Russ. J. Phys. Chem. 87, 1151–1159 (2013). https://doi.org/10.1134/S0036024413070273

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  • DOI: https://doi.org/10.1134/S0036024413070273

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