Abstract
A model for the adsorption of atomic hydrogen on the surfaces of single-walled zig-zag and armchair carbon nanotubes is constructed on the basis of the single-impurity periodic Anderson model. Features of the bands caused by the adsorption of hydrogen atoms in the structure of carbon nanotubes are studied. A reduction in the forbidden gap as a result of adsorption is revealed, and its dependence on the diameter of the semiconducting nanotubes is established. It is concluded that the model can be used to study the adsorption of other monovalent atoms on the surfaces of carbon particles.
This is a preview of subscription content, log in via an institution to check access.
References
L. A. Bol’shov, A. P. Napartovich, A. G. Naumovets, and A. G. Fedorus, Sov. Phys. Usp. 20, 432 (1977).
P. W. Anderson, Phys. Rev. 124, 41 (1961).
P. Harris, Carbon Nanotubes and Related Structures. New Materials for the Twenty-First Century (Cambridge Univ., New York, 1999; Tekhnosfera, Moscow, 2003).
Yu. A. Izyumov, I. I. Chashchin, and D. S. Alekseev, A Generating-Functional Approach in the Theory of Magnetic and Strongly Correlated Systems (Regular. Khaotich. Dinamika, Moscow, Izhevsk, 2006) [in Russian].
S. Yu. Davydov and S. V. Troshin, Phys. Solid State 49, 1583 (2007).
S. Yu. Davydov, G. I. Sabirova, Tech. Phys. Lett. 36, 1154 (2010).
M. B. Belonenko, N. G. Lebedev, and N. N. Yanyushkina, Phys. Solid State 52, 1780 (2010).
N. N. Yanyushkina, M. B. Belonenko, and N. G. Lebedev, Mater. Sci. Appl. 1, 72 (2010).
S. V. Tyablikov, Methods in the Quantum Theory of Magnetism (2nd ed., Nauka, Moscow, 1975; Plenum Press, New York, 1967).
N. F. Stepanov, Quantum Mechanics and Quantum Chemistry (Mir, Moscow, 2001) [in Russian].
N. G. Lebedev, I. V. Zaporotskova, and L. A. Chernozatonskii, Int. J. Quantum. Chem. 96, 149 (2004).
N. G. Lebedev, I. V. Zaporotskova, and L. A. Chernozatonskii, Fulleren. Nanotubes Carbon Nanostruct. 12, 443 (2004).
N. G. Lebedev, I. V. Zaporotskova, and L. A. Chernozatonskii, Int. J. Quantum. Chem. 100, 548 (2004).
O. Guelseren, T. Yildirim, and S. Ciraci, Phys. Rev. B 66, 121401 (2002).
F. H. Yang and R. T. Yang, Carbon 40, 437 (2002).
J. W. Mintmire and C. T. White, Carbon 33, 893 (1993).
O. B. Tomilin and E. E. Muryumin, Phys. Solid State 46, 605 (2006).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © A.V. Pak, N.G. Lebedev, 2013, published in Zhurnal Fizicheskoi Khimii, 2013, Vol. 87, No. 6, pp. 995–1000.
Rights and permissions
About this article
Cite this article
Pak, A.V., Lebedev, N.G. Adsorption model of atomic hydrogen on the surfaces of carbon nanotubes. Russ. J. Phys. Chem. 87, 979–984 (2013). https://doi.org/10.1134/S0036024413060204
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036024413060204