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Changes in the structure of water in aqueous solutions of acetic acid, depending on concentration and temperature according to densitometry, viscosimetry, and IR spectroscopy data

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Abstract

The structural features of aqueous solutions of acetic acid are studied by means of viscosimetry, densimetry, and IR spectroscopy within the temperature range of 283.15–333.15 K and a concentration range of 0–80%. The results from our experiments are used to calculate the parameters of viscous flow activation, the structural temperature, the partial molar volume of acetic acid in the solution, the thermal expansion coefficient, and the energies and lengths of the hydrogen bonds between water molecules. The concentration dependences of these parameters are analyzed. Based on the obtained results, we conclude that acetic acid disrupts the structure of water.

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Authors and Affiliations

  1. Baku State University, AZ 1148, Baku, Azerbaijan

    E. A. Masimov, G. Sh. Khasanov & B. G. Pashaev

Authors
  1. E. A. Masimov
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  2. G. Sh. Khasanov
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  3. B. G. Pashaev
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Correspondence to E. A. Masimov.

Additional information

Original Russian Text © E.A. Masimov, G.Sh. Khasanov, B.G. Pashaev, 2013, published in Zhurnal Fizicheskoi Khimii, 2013, Vol. 87, No. 6, pp. 970–973.

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Masimov, E.A., Khasanov, G.S. & Pashaev, B.G. Changes in the structure of water in aqueous solutions of acetic acid, depending on concentration and temperature according to densitometry, viscosimetry, and IR spectroscopy data. Russ. J. Phys. Chem. 87, 948–951 (2013). https://doi.org/10.1134/S0036024413060186

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  • DOI: https://doi.org/10.1134/S0036024413060186

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