Skip to main content
Log in

Catalytic activity of Co/SiO2 and Co/TiO2 nanosized systems in the oxidation of carbon monoxide

  • Physical Chemistry of Nanoclusters and Nanomaterials
  • Published:
Russian Journal of Physical Chemistry A Aims and scope Submit manuscript

Abstract

The effects of the preparation procedure, active component concentration, and conditions of formation of nanosized cobalt-containing systems based on TiO2 and SiO2 mesoporous powders on their catalytic activity in the oxidation of carbon monoxide were studied. The active phase in the systems was cobalt spinel CoCo2O4 found in all samples. High catalytic activity was found in the samples characterized by relatively high contents of surface active centers (cobalt cations with octahedral surroundings).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. G. A. El-Shobaky, G. A. Fagal, and H. Amin Nabil, J. Chem. Soc. Pak. 11, 107 (1989).

    CAS  Google Scholar 

  2. L. P. Oleksenko and L. V. Lutsenko, Khim. Fiz. Tekhnol. Poverkhn., No. 10, 132 (2004).

    Google Scholar 

  3. Chen-Bin Wang, Chin-Wei Tang, Hsin-Chi Tsai, et al., Catal. Lett. 107, 223 (2006).

    Article  CAS  Google Scholar 

  4. Yeong-Jey Chen, Dai-en Wu, and Chuin-tih Yeh, Rev. Ads. Mater. Sci. 5, 41 (2003).

    CAS  Google Scholar 

  5. M. J. Pollard, B. Weinstock, A. Bitterwolf, E. Thomas, et al., J. Catal. 254, 218 (2008).

    Article  CAS  Google Scholar 

  6. G. Will, N. Masciocchi, W. Parrish, and M. Hart, J. Appl. Crystallogr. 20, 394 (1987).

    Article  CAS  Google Scholar 

  7. W. L. Smith and A. D. Hobson, Acta. Crystallogr. B 29, 362 (1973).

    Article  CAS  Google Scholar 

  8. N. Koizumi, Sh. Suzuki, Yu. Ibi, et al., J. Synchrotron. Rad. 19, 74 (2012).

    Article  CAS  Google Scholar 

  9. Feng Yingjun, Li Liang, Niu Shufan, et al., Appl. Catal. B: Environ. 111–112, 461 (2012).

    Google Scholar 

  10. Yu. Gnatyuk, N. Smirnova, A. Eremenko, et al., Ads. Sci. Technol. 23, 497 (2005).

    Article  CAS  Google Scholar 

  11. A. A. Alekseenko, A. A. Boiko, and E. N. Poddenezhnyi, Functional Materials Based on Silicon Dioxide, Synthesized by Sol-Gel Method (GGTU im. Sukhogo, Gomel’, 2004) [in Russian].

    Google Scholar 

  12. S. J. Gregg and K. S. W. Sing, Adsorption, Surface Area and Porosity (Academic, London, 1967).

    Google Scholar 

  13. M. A. Barakat, G. Hayes, and Shah S. Ismat, J. Nanosci. Nanotechnol. 10, 1 (2005).

    Google Scholar 

  14. M. A. Mohamed, S. A. Halawy, and M. M. Ebrahim, J. Therm. Anal. 41, 387 (1994).

    Article  CAS  Google Scholar 

  15. R. Euler, The Chemistry of Silica (Wiley, New York, 1979; Mir, Moscow, 1982).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to A. A. Kelyp.

Additional information

Original Russian Text © A.A. Kelyp, N.P. Smirnova, L.P. Oleksenko, L.V. Lutsenko, E.I. Oranskaya, A.P. Ripko, 2013, published in Zhurnal Fizicheskoi Khimii, 2013, Vol. 87, No. 6, pp. 1027–1032.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kelyp, A.A., Smirnova, N.P., Oleksenko, L.P. et al. Catalytic activity of Co/SiO2 and Co/TiO2 nanosized systems in the oxidation of carbon monoxide. Russ. J. Phys. Chem. 87, 1015–1020 (2013). https://doi.org/10.1134/S0036024413060125

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036024413060125

Keywords

Navigation