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Effect of ionic strength on the thermodynamic characteristics of complexation between Fe(III) ion and nicotinamide in water-ethanol and water-dimethyl sulfoxide mixtures

  • Physical Chemistry of Solutions
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Abstract

Solutions of iron(III) perchlorate in water, water-ethanol, and water-dimethyl sulfoxide solvents (\(x_{H_2 O} \) = 0.7 and 0.25 mole fractions) at ionic strength values I = 0.1, 0.25, and 0.5 are studied by IR spectroscopy. Analysis of the absorption bands of perchlorate ion shows that it does not participate in association processes. It is demonstrated that in the range of ionic strength values between 0 and 0.5 (NaClO4), it affects neither the results from potentiometric titration to determine the stability constants of the iron(III)-nicotinamide complex nor the thermal effects of complexation determined via direct calorimetry in a binary solvent containing 0.3 mole fractions (m.f.) of a non-aqueous component.

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Authors and Affiliations

  1. Research Institute of Thermodynamics and Kinetics of Chemical Processes, Ivanovo State University of Chemistry and Technology, Ivanovo, 153000, Russia

    G. A. Gamov, K. V. Grazhdan, M. A. Gavrilova, S. V. Dushina & V. A. Sharnin

  2. Cracow University of Technology, 31-155, Cracow, Poland

    A. Baranski

Authors
  1. G. A. Gamov
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  2. K. V. Grazhdan
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  3. M. A. Gavrilova
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  4. S. V. Dushina
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  5. V. A. Sharnin
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  6. A. Baranski
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Corresponding author

Correspondence to K. V. Grazhdan.

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Original Russian Text © G.A. Gamov, K.V. Grazhdan, M.A. Gavrilova, S.V. Dushina, V.A. Sharnin, A. Baranski, 2013, published in Zhurnal Fizicheskoi Khimii, 2013, Vol. 87, No. 6, pp. 989–994.

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Gamov, G.A., Grazhdan, K.V., Gavrilova, M.A. et al. Effect of ionic strength on the thermodynamic characteristics of complexation between Fe(III) ion and nicotinamide in water-ethanol and water-dimethyl sulfoxide mixtures. Russ. J. Phys. Chem. 87, 967–972 (2013). https://doi.org/10.1134/S0036024413060101

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  • DOI: https://doi.org/10.1134/S0036024413060101

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