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Chromatographic properties of mesoporous silica gel modified with acetylacetonates of europium and copper

  • Physical Chemistry of Separation Processes: Chromatography
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Abstract

New mesoporous materials prepared from tetraethoxysilane, i.e., sorbents obtained with the use of surfactants, are synthesized. Their chromatographic polarity is assessed quantitatively. Their Kovats retention indices and Rohrschneider polarity coefficients are calculated. Based on physicohemical data, it is demonstrated that modifying supports with metal chelates changes the structure and properties of the initial sorbents: the differential molar Gibbs free energies rise considerably for sorbent modified with copper acetylacetonate with respect to ethanol (−ΔG′ i = 7.09 kJ/mol) and nitromethane (−ΔG′ i = 6.75 kJ/mol), relative to the initial silica gel (5.43 and 4.15 kJ/mol, respectively).

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Authors and Affiliations

  1. Tomsk State University, Tomsk, 634050, Russia

    Zh. V. Faustova & Yu. G. Slizhov

  2. Tomsk Polytechnic University, Tomsk, Russia

    M. A. Gavrilenko

Authors
  1. Zh. V. Faustova
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  2. Yu. G. Slizhov
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  3. M. A. Gavrilenko
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Correspondence to Zh. V. Faustova.

Additional information

Original Russian Text © Zh.V. Faustova, Yu.G. Slizhov, M.A. Gavrilenko, 2013, published in Zhurnal Fizicheskoi Khimii, 2013, Vol. 87, No. 7, pp. 1236–1238.

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Faustova, Z.V., Slizhov, Y.G. & Gavrilenko, M.A. Chromatographic properties of mesoporous silica gel modified with acetylacetonates of europium and copper. Russ. J. Phys. Chem. 87, 1215–1217 (2013). https://doi.org/10.1134/S0036024413060083

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  • DOI: https://doi.org/10.1134/S0036024413060083

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