Abstract
The kinetics of sorption of triterpene saponin by the polymer sorbent NM-200 is considered. The influence of the surface activity of glycoside on the rate of formation and structure of the adsorption layer on the sorbent’s surface is established. The rate-determining step of sorption is found to be diffusion into the sorbent grain. The value of the activation energy demonstrates the determining role of dispersion forces in the interaction between triterpene saponin and the polymer sorbent MN-200.
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N. V. Mironenko, T. A. Brezhneva, T. N. Poyarkova, and V. F. Selemenev, Pharm. Chem. J. 44, 157 (2010).
N. V. Mironenko, T. A. Brezhneva, I. A. Mikhina, and V. F. Selemenev, Zav. Lab. Diagn. Mater. 75(5), 19 (2009).
N. V. Mironenko, T. A. Brezhneva, and V. F. Selemenev, Khim. Rastit. Syr’ya, No. 3, 153 (2011).
E. Yu. Andreeva, Extended Abstract of Candidate’s Dissertation in Chemistry (Mosc. State Univ. Lomonosova, Moscow, 2011).
A. V. Pastukhov, Extended Abstract of Doctoral Dissertation in Chemistry (Inst. Elementoorg. Soedin. Nesmeyanova, Moscow, 2008).
O. A. Filippov, T. I. Tikhomirova, G. I. Tsizin, and Yu. A. Zolotov, J. Anal. Chem. 58, 398 (2003).
N. B. Ferapontov, A. N. Gagarin, A. N. Gruzdeva, et al., in Proceedings of the 8th Regional Conference on Problems of the Chemistry and Chemical Technology (Voronezh, 2000), p. 99.
A. M. Koganovskii and N. A. Klimenko, Physicochemical Fundamentals for Surfactant Separation from Aqueous Solutions and Waste Waters (Naukova Dumka, Kiev, 1978) [in Russian].
A. M. Koganovskii, N. A. Klimenko, T. M. Levchenko, et al., Adsorption of Organic Substances from Water (Khimiya, Leningrad, 1990) [in Russian].
G. E. El’kin, N. V. Glazova, and L. V. Kurdyavka, Zh. Fiz. Khim. 68, 1782 (1994).
V. V. Podlesnyuk, N. A. Klimenko, L. E. Fridman, et al., Kolloidn. Zh. 53, 1075 (1991).
F. Helfferich, Ion Exchange (Chemie, Weinheim Bergstr., 1959; McGraw-Hill, New York, 1962).
G. S. Libinson, Sorption of Organic Compounds by Ion Exchangers (Meditsina, Moscow, 1979) [in Russian].
G. V. Samsonov, Sorbtion and Chromatographical Methods of Physicochemical Biotechnology (Nauka, Leningrad, 1986) [in Russian].
S. I. Karpov, M. V. Matveeva, and V. F. Selemenev, Russ. J. Phys. Chem. A 75, 266 (2001).
O. A. Pisarev, G. V. Samsonov, L. P. Bogdanova, et al., Zh. Prikl. Khim. 66, 2825 (1993).
O. A. Pisarev and N. V. Glazova, Sorbts. Khromatogr. Protsessy 1, 415 (2001).
G. V. Samsonov, E. B. Trostyanskaya, and G. E. El’kin, Ion Exchange: Adsorption of Organic Substances (Nauka, Leningrad, 1969) [in Russian].
Ya. I. Gerasimov, V. P. Dreving, and E. N. Eremin, Course of Physical Chemistry (Nauka, Moscow, 1970), Vol. 2 [in Russian].
G. V. Slavinskaya and O. V. Kurenkova, Sorbtsion. Khromatogr. Protsessy 10(4), 602 (2010).
V. A. Kireev, Course of Physical Chemistry (Khimiya, Moscow, 1975).
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Original Russian Text © N.V. Mironenko, T.A. Brezhneva, V.F. Selemenev, 2013, published in Zhurnal Fizicheskoi Khimii, 2013, Vol. 87, No. 3, pp. 387–390.
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Mironenko, N.V., Brezhneva, T.A. & Selemenev, V.F. Kinetics of the sorption of triterpene saponin by hypercrosslinked polystyrene. Russ. J. Phys. Chem. 87, 368–371 (2013). https://doi.org/10.1134/S0036024413030175
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DOI: https://doi.org/10.1134/S0036024413030175