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Molecular structure and thermal behavior of N-Benzoyl-3,3-dinitroazetidine

  • Structure of Matter and Quantum Chemistry
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Abstract

N-Benzoyl-3,3-dinitroazetidine (BDNAZ) has been synthesized and characterized by elemental analysis, FT-IR spectroscopy, 1H NMR and X-ray single crystal diffraction technique. BDNAZ crystallizes in the monoclinic space group P21/c. Its thermal behavior was studied under a non-isothermal condition by DSC and TG/DTG methods, the value of E a and A of the exothermic decomposition reaction of BDNAZ are 143.19 kJ mol−1 and 1014.34 s−1, respectively. The specific heat capacity of BDNAZ was determined with a continuous C p mode of micro-calorimeter and theoretical calculation. The adiabatic time-to-explosion was evaluated as 109.9–124.4 s.

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Authors and Affiliations

  1. School of Chemical Engineering, Shaanxi Key Laboratory of Physico-lnorganic Chemistry, Northwest University, Xi’an, 710069, China

    Biao Yan, Ningning Zhao, Tao Mai, Kangzhen Xu, Haixia Ma & Jirong Song

  2. School of Chemistry and Chemical Engineering, Yulin University, Yulin, 719000, China

    Biao Yan

  3. Conservation Technology Department, the Palace Museum, 4 Jingshan Qianjie Beijing, 100009, Beijing, China

    Jirong Song

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  1. Biao Yan
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  2. Ningning Zhao
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  3. Tao Mai
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  4. Kangzhen Xu
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  5. Haixia Ma
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Correspondence to Biao Yan.

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Yan, B., Zhao, N., Mai, T. et al. Molecular structure and thermal behavior of N-Benzoyl-3,3-dinitroazetidine. Russ. J. Phys. Chem. 86, 1962–1968 (2012). https://doi.org/10.1134/S0036024412130055

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  • DOI: https://doi.org/10.1134/S0036024412130055

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