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The inclusion of density fluctuations in the theory of adsorption of laterally interacting molecules on microcrystalline particles

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Abstract

Equations for the isotherms of adsorption of pure substances on small inhomogeneous crystalline particles with taking into account density fluctuations and intermolecular interactions in the quasi-chemical approximation were obtained for the first time.

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References

  1. Yu. K. Tovbin, Theory of Physical Chemistry Processes at a Gas-Solid Surface Interface (CRC Press, Boca Raton, FL, 1991; Nauka, Moscow, 1990).

    Google Scholar 

  2. Yu. K. Tovbin, Russ. J. Phys. Chem. A 84, 1993 (2010).

    Article  CAS  Google Scholar 

  3. Yu. K. Tovbin, Russ. J. Phys. Chem. B 4, 1033 (2010).

    Article  Google Scholar 

  4. Yu. K. Tovbin and A. B. Rabinovich, Russ. J. Phys. Chem. A 84, 2166 (2010).

    Article  CAS  Google Scholar 

  5. Yu. K. Tovbin and A. B. Rabinovich, Russ. J. Phys. Chem. A 85, 1977 (2011).

    Article  CAS  Google Scholar 

  6. T. L. Hill, J. Chem. Phys. 36, 3182 (1962).

    Article  CAS  Google Scholar 

  7. T. L. Hill, Thermodynamics of Small Systems, Part 1 (Benjamin, New York, Amsterdam, 1963).

    Google Scholar 

  8. T. L. Hill, Thermodynamics of Small Systems, Part 2 (Benjamin, New York, Amsterdam, 1964).

    Google Scholar 

  9. Yu. K. Tovbin, Prot. Met. Phys. Chem. Surf. 47, 141 (2011).

    Article  CAS  Google Scholar 

  10. T. L. Hill, Statistical Mechanics. Principles and Selected Applications (McGraw-Hill, New York, 1956; Inostr. Liter., Moscow, 1960).

    Google Scholar 

  11. L. D. Landau and E. M. Lifshitz, Course of Theoretical Physics, Vol. 5: Statistical Physics (Pergamon, Oxford, 1980; Nauka, Moscow, 1995).

    Google Scholar 

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Authors and Affiliations

  1. Karpov Research Institute of Physical Chemistry, ul. Vorontsovo pole 10, Moscow, 105064, Russia

    Yu. K. Tovbin

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  1. Yu. K. Tovbin
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Correspondence to Yu. K. Tovbin.

Additional information

Original Russian Text © Yu.K. Tovbin, 2012, published in Zhurnal Fizicheskoi Khimii, 2012, Vol. 86, No. 7, pp. 1301–1304.

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Tovbin, Y.K. The inclusion of density fluctuations in the theory of adsorption of laterally interacting molecules on microcrystalline particles. Russ. J. Phys. Chem. 86, 1180–1183 (2012). https://doi.org/10.1134/S0036024412070291

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  • DOI: https://doi.org/10.1134/S0036024412070291

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