Abstract
Kinetic studies of hydrogen absorption by porous nickel catalyst establish that there are three regions on kinetic curves of the process differing in their regularities of adsorption. The dependence of the observed rate of hydrogen absorption on the adsorbate amount is formally described by a first order kinetic equation, and the absorption rate constants corresponding to distinct parts of the kinetic curve differ by 1–2 orders of magnitude. The obtained data are explained using the concept that hydrogen adsorption on nickel active centers proceeds with three forms of adsorption.
Similar content being viewed by others
References
D. V. Sokol’skii, Hydrogenation in Solutions (Nauka, Alma-Ata, 1979), p. 198 [in Russian].
I. N. Bazanova, K. N. Belonogov, and V. P. Gostikin, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 27 (1984).
I. A. Makaryan, V. I. Savchenko, Kh. A. Grikenshtein, et al., Russ. Chem. Bull. 32, 692 (1983).
V. P. Gostikin, M. P. Nemtseva, O. V. Lefedova, et al., Kinet. Catal. 39, 690 (1998).
I. F. Tupitsyn and I. P. Tverdovskii, Zh. Fiz. Khim. 33, 2573 (1959).
E. F. Yakubenok, Yu. A. Podvyazkin, and I. I. Yukel’son, Zh. Fiz. Khim. 45, 285 (1971).
L. Kh. Freidlin and N. I. Zimenova, Dokl. Akad. Nauk 74, 965 (1950).
P. Mars, J. F. Scholten, and P. Zwitering, in Actes du 2-me Congrès international de catalyse (Technip, Paris, 1961), Vol. 1, p. 1245.
N. V. Korovin, Elektrokhimiya 8, 552 (1972).
M. V. Ulitin, A. V. Barbov, V. P. Gostikin, et al., Zh. Prikl. Khim. 66, 497 (1993).
M. V. Ulitin and V. P. Gostikin, in Problems of Kinetics and Catalysis (Ivanovo, 1983), p. 78 [in Russian].
C. N. Satterfield, Mass Transfer in Heterogeneous Catalysis (MIT Press, Cambridge, MA, 1970; Khimiya, Moscow, 1976).
A. V. Barbov, M. V. Ulitin, and V. E. Nabilkov, Russ. J. Phys. Chem. A 71, 367 (1997).
L. V. Babenkova and I. N. Blagoveshchenskaya, Zh. Fiz. Khim. 58, 947 (1984).
I. Harris, Appl. Phys. 47, 63 (1988).
G. C. Bond and P. B. Wells, in Catalysis. Physical Chemistry of Heterogeneous Catalysis (Mir, Moscow, 1987), p. 351 [in Russian].
C. F. Melius, I. M. Moscovitz, and A. B. Mortola, Surf. Sci. 5, 279 (1976).
W. H. Weinberg and R. P. Merill, Surf. Sci. 33, 493 (1972).
Z. Paal, in Mechanism of Catalysis, Part 2: Investigation Methods for Catalytic Reactions (Nauka, Novosibirsk, 1984), p. 112 [in Russian].
W. Aner and H. Z. Grabke, Ber. Bunsenges. Phys. Chem. 78, 58 (1974).
K. H. Rieder and W. Sicker, Surf. Sci. 164, 58 (1985).
Y. Yoneda, J. Catal. 9, 51 (1967).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © M.V. Ulitin, Yu.E. Romanenko, O.V. Lefedova, 2012, published in Zhurnal Fizicheskoi Khimii, 2012, Vol. 86, No. 6, pp. 1060–1065.
Rights and permissions
About this article
Cite this article
Ulitin, M.V., Romanenko, Y.E. & Lefedova, O.V. Kinetics of hydrogen absorption by porous nickel in an aqueous sodium hydroxide solution. Russ. J. Phys. Chem. 86, 953–958 (2012). https://doi.org/10.1134/S0036024412060271
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036024412060271