Abstract
The adsorption of hetero- and alicyclic thiophene derivatives synthesized for the first time from water-acetonitrile solutions with various compositions on the surface of porous graphitic carbon was studied by the high-performance liquid chromatography method. The retention factor and Henry adsorption constant values and equilibrium constants of quasi-chemical reactions of the adsorption and solvation of the heterocyclic compounds studied were calculated using the Lanin-Nikitin equation. The influence of the structure of hetero- and alicyclic thiophene derivative molecules on their adsorption on the surface of porous graphitic carbon and solvation in water-acetonitrile solutions was discussed. The Lanin-Nikitin model was found to be more informative in the interpretation of the adsorption-chromatographic experiment data compared with the Snyder-Soczewinski and Scott-Kucera models.
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References
M. Michel and B. Buszewski, Adsorption 15, 193 (2009).
Ya. I. Yashin and A. Ya. Yashin, Russ. Chem. Rev. 75, 329 (2006).
T. Hanai, J. Chromatography A 989, 183 (2003).
N. A. El’tekova and Yu. A. El’tekov, Russ. J. Phys. Chem. A 76, 812 (2002).
W. Tomaszewski, V. M. Gun’ko, R. Leboda, and J. Skubiszewska-Zieba, J. Colloid Interface Sci. 285, 261 (2005).
T. Hanai, J. Chromatography A 1030, 13 (2004).
N. S. Emel’yanova, S. V. Kurbatova, B. R. Saifutdinov, and A. V. Yudashkin, Russ. J. Phys. Chem. A 85, 1440 (2011).
S. N. Lanin, M. Y. Ledenkova, and Y. S. Nikitin, J. Chromatography A 797, 3 (1998).
S. N. Lanin, in 100 Years of Chromatography, Ed. by B. A. Rudenko (Nauka, Moscow, 2003), p. 407 [in Russian].
A. V. Kiselev, Intermolecular Interactions in Adsorption and Chromatography (Vysshaya Shkola, Moscow, 1986) [in Russian].
S. V. Kurbatova and B. R. Saifutdinov, Russ. J. Phys. Chem. A 83, 1223 (2009).
M. J. Frisch, G. W. Trucks, H. B. Schlegel, et al., Gaussian 09, Rev. A.02 (Gaussian Inc., Wallingford, CT, 2009).
A. M. Tolmachev, D. A. Firsov, T. A. Kuznetsova, and K. M. Anuchin, Fizikokhim. Poverkh. Zashch. Mater. 45, 177 (2009).
J. Tomasi, B. Mennucci, R. Cammi, and M. Cossi, Computational Approaches to Biological Reactivity, Ed. by G. Naray-Szabo and A. Warshel (Kluwer Academic, Dordrecht, 1997), p. 1.
G. V. Lisichkin, A. Yu. Fadeev, A. A. Serdan, et al., Chemistry of Graft Surface Compounds (Fizmatlit, Moscow, 2003) [in Russian].
J. H. Knox and P. Ross, Adv. Chromatogr. 37, 73 (1997).
B. V. Nekrasov, Principles of General Chemistry (Lan’, St. Petersburg, 2003), Vol. 1 [in Russian].
V. M. Tapilin, Zh. Strukt. Khim. 46, 11 (2005).
C. S. Sychov, V. A. Davankov, N. A. Proskurina, and A. Yu. Mikheeva, LC-GC-Europe 22, 20 (2009).
Structure Self Organization in Solutions and on the Boundary of Phase Division, Ed. by A. Yu. Tsivadze (LKI, Moscow, 2008) [in Russian].
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Original Russian Text © B.R. Saifutdinov, N.S. Emel’yanova, S.V. Kurbatova, A.A. Pimerzin, 2012, published in Zhurnal Fizicheskoi Khimii, 2012, Vol. 86, No. 7, pp. 1270–1279.
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Saifutdinov, B.R., Emel’yanova, N.S., Kurbatova, S.V. et al. The adsorption of hetero- and alicyclic thiophene derivatives from water-acetonitrile solutions on the surface of porous graphitic carbon under high-performance liquid chromatography conditions. Russ. J. Phys. Chem. 86, 1152–1160 (2012). https://doi.org/10.1134/S0036024412060234
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DOI: https://doi.org/10.1134/S0036024412060234