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State of adsorption layers of fatty acids on the surfaces of iron, manganese, and copper ferrites

  • Physical Chemistry of Surface Phenomena
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Abstract

States of adsorbed substances in surface layers arising during the adsorption of oleic, linoleic, and linolenic acids from carbon tetrachloride, heptane, and cyclohexane solutions on the surfaces of iron, manganese, and copper ferrites, are investigated. Adsorption isotherms and two-dimensional state diagrams of surface layers of iron, manganese, and copper ferrites are obtained experimentally. It is shown that the adsorption of fatty acids from solutions in organic solvents proceeds via filling the volume of the ferrites’ porous space with adsorption solutions, while the state of ferrite surface layers changes due to the structural rearrangement of adsorption solutions upon an increase in solute concentration.

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Correspondence to O. V. Balmasova.

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Original Russian Text © O.V. Balmasova, A.G. Ramazanova, V.V. Korolev, 2012, published in Zhurnal Fizicheskoi Khimii, 2012, Vol. 86, No. 7, pp. 1251–1254.

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Balmasova, O.V., Ramazanova, A.G. & Korolev, V.V. State of adsorption layers of fatty acids on the surfaces of iron, manganese, and copper ferrites. Russ. J. Phys. Chem. 86, 1134–1136 (2012). https://doi.org/10.1134/S0036024412060039

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  • DOI: https://doi.org/10.1134/S0036024412060039

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