Abstract
States of adsorbed substances in surface layers arising during the adsorption of oleic, linoleic, and linolenic acids from carbon tetrachloride, heptane, and cyclohexane solutions on the surfaces of iron, manganese, and copper ferrites, are investigated. Adsorption isotherms and two-dimensional state diagrams of surface layers of iron, manganese, and copper ferrites are obtained experimentally. It is shown that the adsorption of fatty acids from solutions in organic solvents proceeds via filling the volume of the ferrites’ porous space with adsorption solutions, while the state of ferrite surface layers changes due to the structural rearrangement of adsorption solutions upon an increase in solute concentration.
Similar content being viewed by others
References
D. I. Husbands, W. Tallis, and J. C. R. Waldsax, Powder Technol. 5, 31 (1971).
K. N. Han and T. W. Healy, J. Colloid Interface Sci. 44, 407 (1973).
O. M. Mikhailik and V. I. Povstugar, Zh. Prikl. Khim. 65, 1714 (1992).
O. M. Mikhailik and V. I. Povstugar, Zh. Prikl. Khim. 65, 1725 (1992).
H. Sugihara, J. Taketomi, and T. Uehori, J. Chem. Soc., Faraday Trans. I 76, 545 (1980).
A. D. Buckland, C. H. Rochester, and S. A. Topham, J. Chem. Soc., Faraday Trans. 1(76), 302 (1980).
M. M. Dubinin, Russ. Chem. Bull. 40, 1 (1991).
D. A. Fridrikhsberg, Course of Colloid Chemistry (Khimiya, Leningrad, 1984) [in Russian].
A. Adamson, The Physical Chemistry of Surfaces (Wiley, New York, 1976).
V. V. Korolev, O. V. Balmasova, and A. G. Ramazanova, Russ. J. Phys. Chem. A 83, 1018 (2009).
O. V. Balmasova, V. V. Korolev, and V. I. Yashkova, Russ. J. Phys. Chem. A 84, 76 (2010).
A. V. Barbov and M. V. Ulitin, Russ. J. Phys. Chem. A 71, 1845 (1997).
O. V. Balmasova and V. V. Korolev, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 52(7), 52 (2009).
Adsorption from Solution at the Solid, Ed. by G. Parfitt and C. R. Rochester (Academic, London, 1983; Mir, Moscow, 1986).
N. Yu. Sharonov, M. Yu. Ulitin, and M. A. Budanov, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 52(4), 11 (2009).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © O.V. Balmasova, A.G. Ramazanova, V.V. Korolev, 2012, published in Zhurnal Fizicheskoi Khimii, 2012, Vol. 86, No. 7, pp. 1251–1254.
Rights and permissions
About this article
Cite this article
Balmasova, O.V., Ramazanova, A.G. & Korolev, V.V. State of adsorption layers of fatty acids on the surfaces of iron, manganese, and copper ferrites. Russ. J. Phys. Chem. 86, 1134–1136 (2012). https://doi.org/10.1134/S0036024412060039
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036024412060039