Abstract
In this paper the photocatalytic degradation of anionic surfactant LABS was studied by a batch process using ZnO nanoparticles with diameter size of 20 nm catalyst on irradiation with UV light and their behavior comparatively examined with respect to ZnO commercial powder. The effect of parameters such as initial surfactant concentration, initial solution pH has been studied. Also degradation at LABS in the presence of an electron acceptor like potassium peroxydisulfate and effect of anion presence on surfactant degradation has been systematically investigated. The obtained result demonstrated a high photocatalytic activity of nanosize semiconducting particles.
This is a preview of subscription content, access via your institution.
References
P. Berth and P. Jeschke, Tenside Surf. Det. 26, 75 (1989).
W. De Wolf and T. Feijtel, Chemosphere 36, 1319 (1998).
K. Vinogdopal and P. V. Kamat, Environ. Sci. Technal. 29, 841 (1995).
M. Muneer, R. Philips, and S. Das, Res. Chem. Termed. 23, 233 (1997).
S. K. Kansal, M. Singh, and D. Sud, J. Hazard. Mater. 141, 581 (2007).
M. Saquib and M. Muneer, Desalination 155, 255 (2003).
H. Lin and S. Liao, J. Photochem. Photobiol. A 174, 82 (2005).
Y. T. Kown, K. Y. Song, W. I. Lee, G. J. Choi, and Y. R. Do, J. Catal. 191, 192 (2000).
B. Liv, T. Torimoto, and H. Yoneyama, J. Photochem. Photobiol. A: Chem. 113, 93 (1998).
M. A. Behnajady, N. Modirshahla, and R. Hamzavi, J. Hazard. Mater. B 133, 226 (2006).
C. A. K. Gouvea, F. Wypych, S.G. Moraes, N. Duran, N. Nagata, and P. Peralta Zamora, Chemosphere 40, 433 (2000).
C. Lizama, J. Freer, J. Beaza, and H. D. Mansilla, Catal. Today 76, 235 (2002).
P. V. Kamat, R. Huehn, and R. Nicolaescu, J. Phys. Chem. B 106, 788 (2002).
R. Comparelli, E. Fahizza, M.L. Curri, P. D. Cozzolli, G. Mascob, and A. Agostiano, Appl. Catal. B: Environ. 62, 144 (2005).
O. A. Fouad, A. A. Ismail, Z. I. Zaki, and R. M. Mohammad, Appl. Catal. B: Environ. 62, 144 (2006).
I. K. Konstantionus and T. A. Alabanis, Appl. B: Environ. 49, 1 (2009).
J. Gimenz, D. Curco, and P. Marco, Water. Sci. Technol. 35, 207 (1997).
N. San, A. Hatipo, G. Kočtruk, and Z. Cinar, J. Photochem. Photobiol. A: Chem. 146, 189 (2002).
C. G. da Silva and J. L. Faria, J. Photochem. Photobiol. A: Chem. 155, 133 (2003).
M. Romero, J. Blanco, B. Sánchez, A. Vidal, S. Malato, A. L. Cardona, and E. García, Solar Energy 66, 169 (1999).
W. Z. Tang, Z. Zhang, H. An, M. O. Quintanta, and D. F. Torres, Environ. Thechnol. 18, 112 (1997).
A. Hagfeldt and M. Cratzel, Chem. Rev. 95, 49 (1995).
G. V. Buxton and R. M. Seller, J. Chem. Soc. Faraday Trans. 81, 449 (1985).
C. Lee and J. Yoon, J. Photochem. Photobiol. A: Chem. 165, 35 (2004).
M. Muneer, R. Philips, and S. Das, Res. Chem. Intermed. 23, 233 (1997).
A. B. Prevot, M. Vincenti, A. Bianciotto, and E. Pramuro, Appl. Catal. B: Environ. 22, 149 (1999).
C. Kormann, D. Bahnemann, and M. Hofmann, Environs. Sci. Technol. 22, 798 (1988).
C. Richard and P. Boule, Solar Cells 38, 431 (1995).
Author information
Authors and Affiliations
Corresponding author
Additional information
The article is published in the original.
Rights and permissions
About this article
Cite this article
Giahi, M., Habibi, S., Toutounchi, S. et al. Photocatalytic degradation of anionic surfactant using zinc oxide nanoparticles. Russ. J. Phys. Chem. 86, 689–693 (2012). https://doi.org/10.1134/S0036024412040103
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036024412040103
Keywords
- zinc oxide nanoparticles
- photocatalytic
- degradation
- LABS