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Molar volumes of aqueous and ethylene glycol solutions of tetrahydrofuran

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Abstract

The densities of ethylene glycol solutions of tetrahydrofuran (THF) with 0–20 mol % THF were measured at 20–60°C and atmospheric pressure to an accuracy of 5 × 10−5 g/cm3. The apparent molar volumes of THF in the solutions were calculated and their concentration and temperature dependences determined. The results were compared with the apparent molar volumes of THF in aqueous systems calculated from the literature data. Minima were found on the concentration dependence of the apparent volume of THF for both aqueous and ethylene glycol solutions and changed differently as the temperature increased. The data obtained were discussed from the standpoint of solvophobic effects in aqueous and ethylene glycol solutions of THF.

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References

  1. M. N. Rodnikova, Zh. Fiz. Khim. 67, 275 (1993).

    CAS  Google Scholar 

  2. M. N. Rodnikova and N. A. Chumaevskii, Zh. Strukt. Khim., Suppl. Iss. 47, 154 (2006).

    Google Scholar 

  3. M. N. Rodnikova, in Structural Self Organization in Solutions and on the Phase Boundaries, Ed. by A. Yu. Tsivadze (RFFI, Moscow, 2008), p. 151 [in Russian].

    Google Scholar 

  4. R. Boese and H.-C. Weiss, Acta Crystallogr. C54 (1998), IUC9800024.

  5. D. Chopra, T. N. Guru, E. Arunan, and R. Klein, J. Mol. Struct. 964, 126 (2010).

    Article  CAS  Google Scholar 

  6. H. J. Geise, W. J. Adams, and L. S. Bartell, Tetrahedron 25, 3045 (1969).

    Article  CAS  Google Scholar 

  7. B. Cadioli, E. Gallinella, C. Coulombeau, et al., J. Phys. Chem. 97, 7844 (1993).

    Article  CAS  Google Scholar 

  8. D. T. Bouron, J. Finney, and A. K. Sopper, J. Am. Chem. Soc. 128, 5119 (2006).

    Article  Google Scholar 

  9. O. Kiyohara, P. D’Arcy, and G. C. Benson, Can. J. Chem. 56, 2803 (1978).

    Article  CAS  Google Scholar 

  10. Aldrich Catalog. Handbook of Fine Chemicals (2006), p. 1160.

  11. F. Franks, Water. Comprehensive Treatise (1975), Vol. 4, p. 1.

    CAS  Google Scholar 

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

    M. N. Rodnikova, M. A. Gunina & T. M. Val’kovskaya

  2. Institute of Solution Chemistry, Ivanovo, Russia

    D. M. Makarov & G. I. Egorov

Authors
  1. M. N. Rodnikova
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  2. M. A. Gunina
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  3. D. M. Makarov
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  4. G. I. Egorov
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  5. T. M. Val’kovskaya
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Corresponding author

Correspondence to M. N. Rodnikova.

Additional information

Original Russian Text © M.N. Rodnikova, M.A. Gunina, D.M. Makarov, G.I. Egorov, T.M. Val’kovskaya, 2011, published in Zhurnal Fizicheskoi Khimii, 2011, Vol. 85, No. 9, pp. 1798–1800.

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Rodnikova, M.N., Gunina, M.A., Makarov, D.M. et al. Molar volumes of aqueous and ethylene glycol solutions of tetrahydrofuran. Russ. J. Phys. Chem. 85, 1676–1678 (2011). https://doi.org/10.1134/S003602441109024X

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  • DOI: https://doi.org/10.1134/S003602441109024X

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