Abstract
The changes that occur under conditions of irradiation in a chromatographic system were considered with the use of a mathematical model for eluents with a wide pH range at constant concentration of complexone. The effect of the concentration of complexone and the behavior of individual components of the mixture under separation were studied at constant pH. The character of the change in the concentrations and pH values in eluates was determined. Experimental data obtained earlier were interpreted on the basis of the above considerations.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
O. V. Kharitonov and L. A. Firsova, Zh. Fiz. Khim. 85(6), 1155 (2011).
O. V. Kharitonov, E. A. Chuveleva, and L. A. Firsova, Zh. Fiz. Khim. 69, 1848 (1995).
V. M. Gelis, G. B. Maslova, P. P. Nazarov, et al., Zh. Fiz. Khim. 51, 38 (1977).
V. M. Gelis and G. B. Maslova, Radiokhimiya 40, 52 (1998).
O. V. Kharitonov, L. A. Firsova, and E. A. Chuveleva, Zh. Fiz. Khim. 83, 1169 (2009) [Russ. J. Phys. Chem. A 83, 1030 (2009)].
B. Tremillion, Separation on Ion Exchange Resins (Mir, Moscow, 1967) [in Russian].
L. A. Firsova, E. A. Chuveleva, P. P. Nazarov, and P. Ya. Glazunov, Zh. Fiz. Khim. 57, 770 (1983).
L. A. Firsova, E. A. Chuveleva, P. P. Nazarov, and P. Ya. Glazunov, Radiokhimiya 27, 648 (1985).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © O.V. Kharitonov, L.A. Firsova, 2011, published in Zhurnal Fizicheskoi Khimii, 2011, Vol. 85, No. 7, pp. 1348–1355.
Rights and permissions
About this article
Cite this article
Kharitonov, O.V., Firsova, L.A. Theoretical analysis of systems of chelation chromatography upon irradiation. Russ. J. Phys. Chem. 85, 1242–1249 (2011). https://doi.org/10.1134/S0036024411070107
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036024411070107