Skip to main content
SpringerLink
Log in

Low-temperature emission of singlet oxygen from the surface of transition metal oxides

  • Short Communications
  • Published:
Russian Journal of Physical Chemistry A Aims and scope Submit manuscript

Abstract

Low-temperature emission of the singlet form of dioxygen 1O2 from the surface of the individual and mixed V and Mo oxides was detected by thermal desorption at 20–350°C. The amount of the desorbing 1O2 and the temperature range of 1O2 emission were found to depend on the composition of the catalyst; the low-temperature 1O2 form can be regenerated after its contact with oxygen.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

References

  1. M. Iwamoto and J. H. Lunsford, J. Phys. Chem. 84, 3079 (1980).

    Article  CAS  Google Scholar 

  2. V. E. Henrich, Rep. Prog. Phys. 48, 1481 (1985).

    Article  CAS  Google Scholar 

  3. A. A. Davydov, Infrared Spectroscopy of Adsorbed Species on the Surfaces of Transition Metal Oxides (Wiley, Chichester, UK, 1990).

    Google Scholar 

  4. C. Louis, T. L. Chang, M. Kermarec, et al., Colloids Surf., A 72, 217 (1993).

    Article  CAS  Google Scholar 

  5. H.-J. Freund, B. Dillmann, O. Seiferth, et al., Catal. Today 32, 1 (1996).

    Article  CAS  Google Scholar 

  6. B. Dillmann, F. Rohr, O. Seiferth, et al., Faraday Disc. 105, 295 (1996).

    Article  CAS  Google Scholar 

  7. M. Haneda, T. Mizushima, and N. Kakuta, J. Chem. Soc., Faraday Trans. 91, 4459 (1995).

    Article  CAS  Google Scholar 

  8. D. Barreca, F. Morazzoni, G. A. Rizzi, et al., Phys. Chem. Chem. Phys. 13, 1743 (2000).

    Google Scholar 

  9. T. Kawabe, K. Tabata, E. Suzuki, et al., J. Phys. Chem. 105, 4239 (2001).

    CAS  Google Scholar 

  10. V. V. Pushkarev, V. I. Kovalchuk, and J. L. d’Itri, J. Phys. Chem. 108, 5341 (2004).

    CAS  Google Scholar 

  11. N. Sheppard, Vibrational Spectroscopy of Adsorbates, Springer Series in Chemical Physics, Vol. 15, Ed. by R. F. Willis (Springer, Berlin, 1980), p. 165.

    Google Scholar 

  12. M. Che and A. J. Tench, Adv. Catal. 31, 77 (1982).

    Article  CAS  Google Scholar 

  13. M. Che and A. J. Tench, Adv. Catal. 32, 1 (1983).

    Article  CAS  Google Scholar 

  14. C. Li, K. Domen, K. Maruya, and T. Onishi, J. Am. Chem. Soc. 111, 683 (1989).

    Article  Google Scholar 

  15. V. M. Bermudez and V. H. Ritz, Chem. Phys. Lett. 73, 160 (1980).

    Article  CAS  Google Scholar 

  16. J. P. S. Badyal, X. Zhang, and R. M. Lambert, Surf. Sci. L15, 225 (1990).

    Google Scholar 

  17. A. F. Carley, S. D. Jackson, M. W. Roberts, and J. O’shea, Chem. Phys. Lett. 141, 454 (2000).

    Google Scholar 

  18. M. Kasha and D. E. Brabham, in Singlet Oxygen, Ed. by H. H. Wasserman and R. W. Murray (Academic, New York, 1979), p. 1.

    Google Scholar 

  19. M. J. Davies, Photochem. Photobiol. Sci. 3, 17 (2004).

    Article  CAS  Google Scholar 

  20. J. R. Kanofsky, J. Biol. Chem. 258, 5991 (1983).

    CAS  Google Scholar 

  21. J. R. Kanofsky, J. Biol. Chem. 259, 5596 (1984).

    CAS  Google Scholar 

  22. J. R. Kanofsky and P. Sima, J. Biol. Chem. 266, 9039 (1991).

    CAS  Google Scholar 

  23. R. W. Redmond and N. J. Gamlin, Photochem. Photobiol. 70, 391 (1999).

    CAS  Google Scholar 

  24. B. Dmuchovsky, M. C. Freerks, E. D. Pierron, et al., J. Catal. 4, 291 (1965).

    Article  CAS  Google Scholar 

  25. S. A. Zav’yalov, I. A. Myasnikov, and L. M. Zav’yalova, Dokl. Akad. Nauk SSSR 284, 378 (1982).

    Google Scholar 

  26. M. V. Vishnetskaya, A. N. Emel’yanov, N. V. Shcherbakov, et al., Zh. Fiz. Khim. 78, 2152 (2004) [Russ. J. Phys. Chem. A 78, 1918 (2004)].

    Google Scholar 

  27. A. N. Romanov, Y. N. Rufov, and V. N. Korchak, Mendeleev Commun. 10(3), 116 (2000).

    Article  Google Scholar 

  28. I. I. Vol’nov, Peroxocomplexes of Chromium, Molybdenum, Wolfram (Nauka, Moscow, 1989) [in Russian].

    Google Scholar 

  29. M. Abu Haija, S. Guimond, Y. Romanyshyn, et al., Surf. Sci. 600, 1497 (2006).

    Article  CAS  Google Scholar 

  30. S. Guimond, M. Abu Haija, S. Kaya, et al., Topics Catal. 38, 117 (2006).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Gubkin Russian State University of Oil and Gas, Moscow, Russia

    O. V. Matrosova

  2. Semenov Institute of Chemical Physics, Moscow, Russia

    Yu. N. Rufov & M. V. Vishnetskaya

Authors
  1. O. V. Matrosova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yu. N. Rufov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. V. Vishnetskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to M. V. Vishnetskaya.

Additional information

Original Russian Text © O.V. Matrosova, Yu.N. Rufov, M.V. Vishnetskaya, 2010, published in Zhurnal Fizicheskoi Khimii, 2010, Vol. 84, No. 12, pp. 2387–2389.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Matrosova, O.V., Rufov, Y.N. & Vishnetskaya, M.V. Low-temperature emission of singlet oxygen from the surface of transition metal oxides. Russ. J. Phys. Chem. 84, 2187–2189 (2010). https://doi.org/10.1134/S0036024410120319

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036024410120319

Keywords

Search

Navigation