Skip to main content
SpringerLink
Log in

The dynamics of water vapor sorption on a composite sorbent in the presence of unsorbable components

  • Physical Chemistry of Surface Phenomena
  • Published:
Russian Journal of Physical Chemistry A Aims and scope Submit manuscript

Abstract

Preliminary mathematical processing of the experimental data on the dynamics of water vapor adsorption on a composite adsorbent was performed. The approximate time dependence of water vapor pressure was constructed. An analytic equation describing changes in the mean temperature of adsorbent grains as a function of the duration of measurements depending on water vapor pressure was obtained, and an asymptotic approximation equation was suggested. The system under consideration was shown to pass two “diffusion” stages in the dynamics of pressure changes and changes in the mean temperature of grains. The characteristic times of the diffusion stages monotonically increased as the fraction of an unadsorbable component in the gas phase of the system grew.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Yu. I. Aristov, L. G. Gordeeva, and M. M. Tokarev, Composites ’salt in Porous Matrix’: Synthesis, Properties, Applications (Sib. Otd. Ross. Akad. Nauk, Novosibirsk, 2008) [in Russian].

    Google Scholar 

  2. I. S. Glaznev and Yu. I. Aristov, Int. J. Heat Mass Transfer 51, 5823 (2008).

    Article  CAS  Google Scholar 

  3. V. K. Bel’nov, Statistical Methods of Parameter Estimation of Mathematic Models of Chemical Processes (Mosk. Gos. Univ., Moscow, 1991) [in Russian].

    Google Scholar 

  4. S. L. Akhnazarova and V. V. Kafarov, Experiment Optimization in Chemistry and Chemical Engineering (Vysshaya shkola, Moscow, 1980; Mir, Moscow, Chicago, 1982).

    Google Scholar 

  5. Yu. I. Aristov, J. Chem. Eng. Jpn. 40, 1242 (2007).

    Article  Google Scholar 

  6. R. Reid, D. Prausnits, and T. Sherwood, The Properties of Gases and Liquids (McGraw-Hill, New York, 1966; Khimiya, Leningrad, 1982).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, Moscow, Russia

    B. N. Okunev, N. M. Voskresenskii, A. P. Gromov & L. I. Kheifets

Authors
  1. B. N. Okunev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. M. Voskresenskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. P. Gromov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. L. I. Kheifets
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to L. I. Kheifets.

Additional information

Original Russian Text © B.N. Okunev, N.M. Voskresenskii, A.P. Gromov, L.I. Kheifets, 2010, published in Zhurnal Fizicheskoi Khimii, 2010, Vol. 84, No. 9, pp. 1764–1769.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Okunev, B.N., Voskresenskii, N.M., Gromov, A.P. et al. The dynamics of water vapor sorption on a composite sorbent in the presence of unsorbable components. Russ. J. Phys. Chem. 84, 1611–1616 (2010). https://doi.org/10.1134/S0036024410090293

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036024410090293

Keywords

Search

Navigation