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The kinetic peculiarities of intermolecular proton transfer from NH groups of octa(m-trifluoromethylphenyl)tetraazaporphin in the nitrogen base-benzene system

  • Chemical Kinetics and Catalysis
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Abstract

The acid-base interaction of octa(m-trifluoromethylphenyl)tetraazaporphin with nitrogen bases in benzene was studied. The rates of intermolecular transfer of sterically screened NH group protons from octa(m-trifluoromethylphenyl)tetraazaporphin to n-butylamine and tert-butylamine were found to be low. A scheme of the process was suggested. The influence of the nature of bases on the kinetic parameters of acid-base interactions was studied.

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Authors and Affiliations

  1. Ivanovo State University of Chemical Technology, Ivanovo, Russia

    O. A. Petrov, O. G. Khelevina & E. L. Kuzmina

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  1. O. A. Petrov
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  2. O. G. Khelevina
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  3. E. L. Kuzmina
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Correspondence to O. A. Petrov.

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Original Russian Text © O.A. Petrov, O.G. Khelevina, E.L. Kuzmina, 2010, published in Zhurnal Fizicheskoi Khimii, 2010, Vol. 84, No. 9, pp. 1654–1659.

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Petrov, O.A., Khelevina, O.G. & Kuzmina, E.L. The kinetic peculiarities of intermolecular proton transfer from NH groups of octa(m-trifluoromethylphenyl)tetraazaporphin in the nitrogen base-benzene system. Russ. J. Phys. Chem. 84, 1506–1510 (2010). https://doi.org/10.1134/S0036024410090104

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  • DOI: https://doi.org/10.1134/S0036024410090104

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