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A thermal and thermochemical study of natural hemimorphite

  • Chemical Thermodynamics and Thermochemistry
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Abstract

A thermal and thermochemical study of natural aqueous hydroxyl-containing diorthosilicate, hemimorphite Zn4[Si2O7](OH)2 · H2O, was performed. The step character of its thermal decomposition was studied using FTIR spectroscopy. Melt solution calorimetry was used to determine the enthalpies of formation from oxides Δf H OXO (298.15 K) = −69.3 ± 9.9 kJ/mol and elements {ie1481-2} (298.15 K) = −3864.3 ± 10.2 kJ/mol.

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Authors and Affiliations

  1. Institute of Comprehensive Exploitation of Mineral Resources, Karaganda, Kazakhstan

    M. R. Bisengalieva

  2. Faculty of Geology, Moscow State University, Moscow, Russia

    L. V. Mel’chakova, L. P. Ogorodova & M. F. Vigasina

Authors
  1. M. R. Bisengalieva
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  2. L. V. Mel’chakova
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  3. L. P. Ogorodova
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  4. M. F. Vigasina
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Corresponding author

Correspondence to L. P. Ogorodova.

Additional information

Original Russian Text © M.R. Bisengalieva, L.V. Mel’chakova, L.P. Ogorodova, M.F. Vigasina, 2010, published in Zhurnal Fizicheskoi Khimii, 2010, Vol. 84, No. 9, pp. 1627–1631.

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Bisengalieva, M.R., Mel’chakova, L.V., Ogorodova, L.P. et al. A thermal and thermochemical study of natural hemimorphite. Russ. J. Phys. Chem. 84, 1481–1484 (2010). https://doi.org/10.1134/S0036024410090050

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  • DOI: https://doi.org/10.1134/S0036024410090050

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