Skip to main content
Log in

Self-organization of the reticular structure of polyurethane

  • Structure of Substances and Quantum Chemistry
  • Published:
Russian Journal of Physical Chemistry A Aims and scope Submit manuscript

Abstract

The morphology of block samples and coatings of reticular polyurethane were studied by transmission electron microscopy. The morphology was correlated with the internal stresses that appeared in the coatings during their formation. A scenario of the self-assembly of complex structures in reticular polymers was suggested. The boundary between the structural elements of the supermolecular level was found to be strained.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. E. H. Erath and M. Robinson, J. Polym. Sci. C, No. 3, 65 (1963).

  2. A. A. Berlin, Vysokomol. Soedin. A 20, 483 (1978).

    CAS  Google Scholar 

  3. V. A. Kargin, M. Azori, N. A. Plate, and S. I. Banduryan, Dokl. Akad. Nauk SSSR 154, 1157 (1964).

    CAS  Google Scholar 

  4. P. I. Zubov and M. R. Kiselev, in Proc. of the 10th All-Union Conf. on Electronic Microscopy (Tashkent, 1976), p. 76.

  5. G. C. Stevens, J. V. M. Champion, and P. Liddel, J. Polym. Sci. Polym. Phys. 20, 327 (1982).

    CAS  Google Scholar 

  6. N. G. Matveeva, M. R. Kiselev, A. A. Berlin, and P. I. Zubov, Dokl. Akad. Nauk SSSR 231, 836 (1976).

    Google Scholar 

  7. V. G. Khozin, Kompoz. Polim. Mater., No. 50, 49 (1991).

  8. M. R. Kiselev and I. I. Bardyshev, Zh. Fiz. Khim. 81, 265 (2007) [Russ. J. Phys. Chem. A 81, 210 (2007)].

    Google Scholar 

  9. S. S. Ivanchev and A. N. Ozerin, Vysokomol. Soedin. 48, 1531 (2006) [Polymer Sci., Ser. B 48, 213 (2006)].

    CAS  Google Scholar 

  10. V. M. Startsev, A. E. Chalykh, S. A. Nenakhov, and A. T. Sanzharovskii, Vysokomol. Soedin. B 17, 836 (1974).

    Google Scholar 

  11. J. S. Mijovic and L. Tsay, Polymer 7, 902 (1981).

    Article  Google Scholar 

  12. T. Takahama and P. H. Geil, Makromol. Chem. Rapid Commun. 3, 389 (1982).

    Article  CAS  Google Scholar 

  13. B. Nabeth, J. P. Pascault, and K. Dusek, J. Polym. Sci. Polym. Phys. 34, 1031 (1996).

    Article  CAS  Google Scholar 

  14. M. R. Vanlandingham, R. F. Eduljee, and J. W. Gillespie, J. Appl. Polym. Sci. 71, 699 (1999).

    Article  CAS  Google Scholar 

  15. P. I. Zubov and L. A. Sukhareva, Structure and Properties of Polymer Coatings (Khimiya, Moscow, 1982), p. 46 [in Russian].

    Google Scholar 

  16. M. R. Kiselev, E. I. Evko, and V. M. Luk’yanovich, Zavod. Lab. 32, 201 (1966).

    CAS  Google Scholar 

  17. Yu. S. Lipatov, Yu. Yu. Kercha, and L. M. Sergeeva, Structure and Properties of Polyurethanes (Naukova Dumka, Kiev, 1970) [in Russian].

    Google Scholar 

  18. I. J. Prosser, J. Mod. Paint Coat., No. 7, 47 (1977).

  19. T. Hugel, G. Strobl, and R. Thomann, Acta Polym. 50, 214 (1999).

    Article  CAS  Google Scholar 

  20. B. Heck, T. Hugel, M. Iijima, and G. Strobl, Polymer 41, 8839 (2000).

    Article  CAS  Google Scholar 

  21. J. Loos, P. C. Thune, J. W. Niemantsverdriet, and P. Lemstra, J. Macromol. 32, 8910 (1999).

    Article  CAS  Google Scholar 

  22. Y. K. Godovsky and S. N. Magonov, Langmuir 16, 3549 (2000).

    Article  CAS  Google Scholar 

  23. S. Sawamura, H. Miyaji, K. Izumi, et al., J. Phys. Soc. Jpn. 67, 3338 (1998).

    Article  CAS  Google Scholar 

  24. Veress K. Dalnoki, J. A. Forrest, M. V. Massa, et al., J. Polym. Sci. Polym. Phys. 39, 2615 (2001).

    Article  Google Scholar 

  25. A. N. Cherkasov, M. G. Vitovskaya, and S. V. Bushin, Vysokomol. Soedin. A 18, 1628 (1976).

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to V. I. Roldugin.

Additional information

Original Russian Text © M.R. Kiselev, V.I. Roldugin, 2010, published in Zhurnal Fizicheskoi Khimii, 2010, Vol. 84, No. 8, pp. 1519–1524.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kiselev, M.R., Roldugin, V.I. Self-organization of the reticular structure of polyurethane. Russ. J. Phys. Chem. 84, 1382–1387 (2010). https://doi.org/10.1134/S0036024410080194

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036024410080194

Keywords

Navigation