Abstract
The values of combustion and formation enthalpy for glycolic acid (I) and glycolide (II) were determined by calorimetry. The temperature dependence of vapor pressures of I and II was obtained using the transpiration method, and the sublimation enthalpies were obtained. The enthalpy of melting of I was found by differential scanning calorimetry. Stable conformers were determined by the ab initio (DFT) method, and combinations of the fundamental oscillations and inertia momenta of I and II conformers were calculated. The full and relative energies of the compounds most stable conformers were found by a composite G3MP2 method, and the enthalpies of formation of I and II in the gaseous state were estimated. The values of the thermodynamic properties in the ideal gas state were determined over the range of 0–1500 K. A thermodynamic analysis was performed for the process of preparation of II from I and the formation of polyglycolide (III) from I and II.
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Original Russian Text © V.N. Emel’yanenko, S.P. Verevkin, E.N. Stepurko, G.N. Roganov, M.K. Georgieva, 2010, published in Zhurnal Fizicheskoi Khimii, 2010, Vol. 84, No. 8, pp. 1434–1441.
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Emel’yanenko, V.N., Verevkin, S.P., Stepurko, E.N. et al. Thermodynamic properties of glycolic acid and glycolide. Russ. J. Phys. Chem. 84, 1301–1308 (2010). https://doi.org/10.1134/S0036024410080054
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DOI: https://doi.org/10.1134/S0036024410080054