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The organization of the surface of multicomponent plasma-electrolytic anode layers on aluminum

  • Colloid Chemistry and Electrochemistry
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Abstract

The elemental composition of characteristic formations on the surface of anodic films containing transition metal compounds (Ni, Cu, Co, Mn, and W) and formed on an aluminum alloy in aqueous electrolytes under the conditions of the action of electric spark and arc discharges (plasma-electrolytic or plasmaelectrochemical oxidation) was studied. The main formations on the surface were fritted structures, pores, caverns covered by “lids” on top, and disperse particles (microgranules). Electrolyte transition metals largely concentrated in caverns, pores, and microgranules. The composition of microgranules was different from that of caverns, pores, and fritted structures. The main elements that formed microgranules were nickel and carbon. Cobalt and manganese were differently built into surface formations. Cobalt replaced nickel in micro-granules, and manganese replaced aluminum in fritted surface structures.

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Authors and Affiliations

  1. Institute of Chemistry, Far East Division, Russian Academy of Sciences, pr. Stoletiya Vladivostoka 159, Vladivostok, 690022, Russia

    I. V. Lukiyanchuk, V. S. Rudnev & P. M. Nedozorov

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  1. I. V. Lukiyanchuk
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  2. V. S. Rudnev
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  3. P. M. Nedozorov
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Correspondence to V. S. Rudnev.

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Original Russian Text © I.V. Lukiyanchuk, V.S. Rudnev, P.M. Nedozorov, 2010, published in Zhurnal Fizicheskoi Khimii, 2010, Vol. 84, No. 6, pp. 1174–1180.

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Lukiyanchuk, I.V., Rudnev, V.S. & Nedozorov, P.M. The organization of the surface of multicomponent plasma-electrolytic anode layers on aluminum. Russ. J. Phys. Chem. 84, 1059–1064 (2010). https://doi.org/10.1134/S0036024410060300

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  • DOI: https://doi.org/10.1134/S0036024410060300

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