Abstract
Cobalt octasulfophenyltetrapyrazinoporphyrazine was shown to be an effective catalyst of nitrite reduction by thiourea dioxide. The intermediate product of nitrite reduction was nitrogen(II) oxide, and the final product was ammonia. The kinetic and activation parameters of catalytic process stages were determined.
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Original Russian Text © E.A. Vlasova, S.V. Makarov, M.N. Malinkina, 2010, published in Zhurnal Fizicheskoi Khimii, 2010, Vol. 84, No. 4, pp. 655–660.
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Vlasova, E.A., Makarov, S.V. & Malinkina, M.N. The kinetics of nitrite reduction by thiourea dioxide in the presence of cobalt octasulfophenyltetrapyrazinoporphyrazine. Russ. J. Phys. Chem. 84, 573–577 (2010). https://doi.org/10.1134/S0036024410040096
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DOI: https://doi.org/10.1134/S0036024410040096