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The oxidation of toluene on transition metal oxides

  • Chemical Kinetics and Catalysis
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Abstract

The oxidation of toluene on pure vanadium and molybdenum oxides was found to follow independent paths; it was benzene ring oxidation on V2O5 and side chain oxidation on MoO3. On mixed xV2O5 · yMoO3 oxides, the main reaction was the addition at the double bond preferably positioned meta rather than one-electron oxidation.

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Authors and Affiliations

  1. Gubkin State University of Oil and Gas, Leninskii pr. 65, Moscow, 117917, Russia

    I. S. Tomskii & M. V. Vishnetskaya

  2. Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina 4, Moscow, Russia

    Yu. N. Rufov

Authors
  1. I. S. Tomskii
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  2. M. V. Vishnetskaya
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  3. Yu. N. Rufov
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Corresponding author

Correspondence to M. V. Vishnetskaya.

Additional information

Original Russian Text © I.S. Tomskii, M.V. Vishnetskaya, Yu.N. Rufov, 2009, published in Zhurnal Fizicheskoi Khimii, 2009, Vol. 83, No. 11, pp. 2057–2061.

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Tomskii, I.S., Vishnetskaya, M.V. & Rufov, Y.N. The oxidation of toluene on transition metal oxides. Russ. J. Phys. Chem. 83, 1868–1872 (2009). https://doi.org/10.1134/S0036024409110107

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  • DOI: https://doi.org/10.1134/S0036024409110107

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