Abstract
The influence of the nature of substituents on the rate of liquid-phase hydrogenation of nitrobenzenes on Raney nickel was studied in an aqueous solution of 2-propanol. Interrelation between the rate of the reaction on the equiaccessible surface of the catalyst and solvation parameters, reactivity indices, and adsorption values of hydrogenated compounds containing electron acceptor (4-nitrobenzoic acid) and electron donor (4-nitroaniline) substituents was considered.
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Original Russian Text © O.V. Lefedova, I.V. Smirnova, M.P. Nemtseva, 2009, published in Zhurnal Fizicheskoi Khimii, 2009, Vol. 83, No. 10, pp. 1911–1914.
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Lefedova, O.V., Smirnova, I.V. & Nemtseva, M.P. The influence of the nature of substituents on adsorbability and the rate of liquid-phase hydrogenation of nitrobenzenes. Russ. J. Phys. Chem. 83, 1727–1730 (2009). https://doi.org/10.1134/S0036024409100173
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DOI: https://doi.org/10.1134/S0036024409100173