Abstract
Changes in the concentration of solute molecules in a glycerol matrix were studied using mass spectrometry of secondary ions that appeared under the bombardment of a sample-solution by primary ions. The objects of study were several organic dyes and glucose oxidase. The concentration of solute molecules in the surface layer of the matrix was determined by the competition between the destruction of analyte molecules by primary ions and the replenishment of the number of undamaged molecules as a result of diffusion from the bulk.
Similar content being viewed by others
References
I. A. Kaltashov and S. J. Eyles, Mass Spectrometry in Biophysics: Conformation and Dynamics of Biomolecules (Wiley Intersci., 2005), p. 458.
L. A. McDonnell, R. M. A. Heeren, R. P. J. de Lange, and I. W. Fletcher, J. Am. Soc. Mass. Spectrom. 17, 1195 (2006).
H. Nygren and P. Malmberg, Trends in Biotechnol. 25, 499 (2007).
J.-L. Guerquin-Kern, T.-D. Wu, C. Quintana, and A. Croisy, Biochim. Biophys. Acta 1724(3), 22 (2005).
A. M. Belu, D. J. Graham, and D. G. Castner, Biomater. 24, 3635 (2003).
A. Panchaud, E. Widmer, M. Kussmann, et al., Int. J. Mass Spectrom. 268, 234 (2007).
H. Nygren, K. Borner, P. Malmberg, and B. Hagenhoff, Appl. Surf. Sci. 252, 6975 (2006).
P. Sjovall, J. Lausmaa, and B. Johansson, Anal. Chem. 76, 258 (2004).
A. M. Herrmann, K. Ritz, N. Nunan, et al., Soil Biol. Biochem. 39(8), 1835 (2007).
D. S. McPhail, Appl. Surf. Sci. 252, 7107 (2006).
N. A. Klyuev and E. S. Brodskii, Ross. Khim. Zh. 46(4), 57 (2002).
R. Cozzolino, R. T. Gallagher, and T. Drewello, Eur. J. Mass. Spectrom. 12(1), 31 (2006).
R. Frański, A. Szymański, B. Gierczyk, et al., J. Mass Spectrom. 37(4), 372 (2002).
M. V. Kosevich, V. V. Chagovets, V. S. Shelkovsky, et al., Rapid Commun. Mass Spectrom. 21, 466 (2007).
G. Suizdak, Mass Spectrometry for Biotechnology (Academic, New York, 1996).
V. N. Mel’nikov, V. A. Litvinov, V. T. Koppe, et al., Vestnik KhNU, Ser. Yadra, Chastitsy, Polya, No. 721, 95 (2006).
V. N. Melnykov, V. A. Litvinov, V. T. Koppe, et al., in Proc. of the 4th Eur. Workshop on Secondary Ion Mass Spectrometry SIMS Europe 2004 (Münster, 2004), p. 91.
A. Benninghoven, Surf. Sci. 35, 427 (1973).
M. Henry, C. Dupont-Gillain, and P. Bertrand, Langmuir 19, 6271 (2003).
V. N. Melnykov, V. A. Litvinov, V. T. Koppe, et al., in Proc. of the 4th Eur. Workshop on Secondary Ion Mass Spectrometry SIMS Europe, 2004 (Münster, 2004), p. 95.
V. A. Pokrovskii and V. V. Mosin, Teor. Eksp. Khim., No. 1, 62 (1987).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © V.N. Mel’nikov, V.A. Litvinov, V.T. Koppe, V.V. Bobkov, 2009, published in Zhurnal Fizicheskoi Khimii, 2009, Vol. 83, No. 6, pp. 1115–1120.
Rights and permissions
About this article
Cite this article
Mel’nikov, V.N., Litvinov, V.A., Koppe, V.T. et al. Secondary ion mass spectrometry of organic materials with the use of a glycerol matrix. Russ. J. Phys. Chem. 83, 979–983 (2009). https://doi.org/10.1134/S0036024409060193
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036024409060193