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Luminescence of antimony(III) halide complexes with aniline

  • Photochemistry and Magnetochemistry
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Abstract

The antimony(III) chloride and bromide complexes with aniline, (C6H5NH3)2SbCl5·(C6H5NH3)Cl·H2O (I) and (C6H5NH3)2SbBr5 (II), were synthesized, and their spectral luminescence properties were studied. An interesting peculiarity of I and II is the possibility of selective excitation of luminescence in the π system of the (C6H5NH3)+ outer sphere anilinium cation and intrinsic luminescence of the s 2 ion. The population scheme for the luminescent antimony 3 P 1 level in I and II is discussed using the luminescence, UV, and photoelectron spectroscopy data.

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Authors and Affiliations

  1. Institute of Chemistry, Far East Division, Russian Academy of Sciences, pr. Stoletiya Vladivostoka 159, Vladivostok, 690022, Russia

    T. V. Sedakova, A. G. Mirochnik & V. E. Karasev

Authors
  1. T. V. Sedakova
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  2. A. G. Mirochnik
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  3. V. E. Karasev
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Correspondence to T. V. Sedakova.

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Original Russian Text © T.V. Sedakova, A.G. Mirochnik, V.E. Karasev, 2009, published in Zhurnal Fizicheskoi Khimii, 2009, Vol. 83, No. 2, pp. 380–382.

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Sedakova, T.V., Mirochnik, A.G. & Karasev, V.E. Luminescence of antimony(III) halide complexes with aniline. Russ. J. Phys. Chem. 83, 308–310 (2009). https://doi.org/10.1134/S0036024409020289

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  • DOI: https://doi.org/10.1134/S0036024409020289

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