Abstract
The interaction of water with solid Novocaine hydrochloride was studied isopiestically over a wide range of solvent relative activities. The Gibbs energy of water interaction with Novocaine hydrochloride crystals was calculated. A scheme of intermolecular interactions in the water-Novocaine hydrochloride system was suggested.
Similar content being viewed by others
References
V. K. Abrosimov, V. F. Agafonov, and R. V. Chumakov, Biologically Active Substances in Solutions: Structure, Thermodynamics, Reactivity (Nauka, Moscow, 2001) [in Russian].
E. M. Shapovalova, Abstracts of Papers, International Symposium “Medicine and Health Protection 2000” (Tyumen’sk. Gos. Med. Akad., Tyumen’, 2000), No. 4, p. 35.
V. Luminita, M. Dana, V. Irinel, and S. Carmencita, Pev. Roum. Chim. 47(8–9), 911 (2002).
I. F. Abdullin, N. N. Chernysheva, and G. K. Budnikov, Zh. Anal. Khim. 57(7), 750 (2002) [J. Anal. Chem. 57 (7), 629 (2002)].
R. Pohloudek-Fabini and Th. Beyrich, Organische Analyse (Akademische Verlagsgesellschaft Geest & Porting K-G, Leipzig, 1975; Khimiya, Leningrad, 1981).
A. N. Kirgintsev, Essays on Thermodynamics of Aqueous Saline Systems (Nauka, Novosibirsk, 1976) [in Russian].
K. Nakanishi, Infrared Absorption Spectroscopy (Holden-Day, San Francisco, 1962; Mir, Moscow, 1965).
A. L. Smith, Applied Infrared Spectroscopy: Fundamentals, Techniques, and Analytical Problem-Solving, Vol. 54 of Chemical Analysis (Wiley, New York, 1979; Mir, Moscow, 1982).
S. J. Gregg and K. S. W. Sing, Adsorption, Surface Area, and Porosity, 2nd ed. (Academic, New York, 1982; Mir, Moscow, 1984).
Kh. Uedaira, Zh. Fiz. Khim. 42(12), 3024 (1968).
Advances and Problems in the Theory of Solvation: Structural and Dynamic Aspects, Ed. by V. K. Abrosimov, A. G. Krestov, G. A. Al’per, et al. (Nauka, Moscow, 1998) [in Russian].
O. V. Kulikov, V. G. Badelin, and G. A. Krestov, Zh. Fiz. Khim. 36(3), 394 (1991).
I. S. Gulyi and V. M. Klimovich, Zh. Strukt. Khim. 32(5), 69 (1991).
H. S. Harned and B. B. Owen, The Physical Chemistry of Electrolytic Solutions, 2nd ed. (Reinhold, New York, 1950; Inostrannaya Literatura, Moscow, 1952).
Biochemical Thermodynamics, Ed. by M. N. Jones, (Elsevier, Amsterdam, 1979; Mir, Moscow, 1982).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © T.A. Krysanova, D.L. Kotova, V.F. Selemenev, 2009, published in Zhurnal Fizicheskoi Khimii, 2009, Vol. 83, No. 2, pp. 286–289.
Rights and permissions
About this article
Cite this article
Krysanova, T.A., Kotova, D.L. & Selemenev, V.F. The thermodynamic characteristics of swelling of novocaine hydrochloride crystals brought into isopiestic contact with water-salt solutions. Russ. J. Phys. Chem. 83, 220–222 (2009). https://doi.org/10.1134/S0036024409020137
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036024409020137