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The thermodynamic properties and thermal decomposition of octachlorotrisilane Si3Cl8

  • Chemical Thermodynamics and Thermochemistry
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Abstract

The standard enthalpies of formation of liquid and gaseous octachlorotrisilane were estimated, Δf H o (298.15, Si3Cl8, g) = −1397(9) kJ/mol and Δf H o (298.15, Si3Cl8, l) = −1447(9) kJ/mol. The decomposition of Si3Cl8 over the temperature range 400–1000 K was studied theoretically.

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Authors and Affiliations

  1. Glushko Thermocenter, Institute of High Energy Density, Joint Institute of High Temperatures, Russian Academy of Sciences, ul. Izhorskaya 13/19, Moscow, 127412, Russia

    Yu. S. Ezhov

  2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 117907, Russia

    E. P. Simonenko & V. G. Sevast’yanov

  3. Lomonosov State Academy of Fine Chemical Technology, pr. Vernadskogo 86, Moscow, 117571, Russia

    E. P. Simonenko & V. G. Sevast’yanov

Authors
  1. Yu. S. Ezhov
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  2. E. P. Simonenko
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  3. V. G. Sevast’yanov
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Correspondence to Yu. S. Ezhov.

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Original Russian Text © Yu.S. Ezhov, E.P. Simonenko, V.G. Sevast’yanov, 2009, published in Zhurnal Fizicheskoi Khimii, 2009, Vol. 83, No. 2, pp. 242–245.

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Ezhov, Y.S., Simonenko, E.P. & Sevast’yanov, V.G. The thermodynamic properties and thermal decomposition of octachlorotrisilane Si3Cl8 . Russ. J. Phys. Chem. 83, 179–181 (2009). https://doi.org/10.1134/S003602440902006X

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  • DOI: https://doi.org/10.1134/S003602440902006X

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