Abstract
The C-C cross coupling reaction between bromobenzene and styrene in the presence of Pd deposited on mesoporous acetylene soot (Pd/C) occurred in a tetraalkylammonium ionic liquid (IL) as a truly heterogeneous catalytic process. The active palladium form was not transferred into the reaction solution. Deposited palladium activation was observed when the Pd/C catalyst was preliminarily heated in the IL in the presence of dibutylamine as a base.
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Aslanov, L.A., Valetskii, P.M., Volkov, V.V. et al. The heterogeneous catalytic heck reaction in an ionic liquid. Russ. J. Phys. Chem. 82, 2238–2242 (2008). https://doi.org/10.1134/S0036024408130141
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DOI: https://doi.org/10.1134/S0036024408130141