Skip to main content
Log in

Composite photocalysts based on the nanostructural titanium dioxide and zirconium phosphate

  • Physical Chemistry of Nanotechnologies
  • Published:
Russian Journal of Physical Chemistry A, Focus on Chemistry Aims and scope Submit manuscript

Abstract

A series of composite photocatalysts based on titanium dioxide deposited on the surface of a zirconium phosphate support were synthesized under different synthesis and heat-treatment conditions. The study of the photodestruction kinetics of Rhodamine C showed that the synthesized composites possess high photocatalytic activity that is competitive with the activity of a commercial Hombikat UV100 photocatalyst. The composites based on zirconium phosphate treated with isopropanol at the precipitation stage whereupon heated at 550°C exhibit the highest photocatalytic activity after heating at 750°C. It was found that such zirconium phosphate support has the largest specific surface area (270 m2/g). After heating at 550°C, the surface becomes more stable to the subsequent heating to 750°C, which is necessary for the most complete crystallization of TiO2 ensuring its high photocatalytic characteristics.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. M. Bekbolet, M. Lindner, D. Weichgrebe, and D. W. Bahnemann, Sol. Energy 56(5), 455 (1996).

    Article  CAS  Google Scholar 

  2. D. W. Bahnemann, S. N. Kholuiskaya, R. Dillert, et al., Appl. Catal., B 36, 161 (2002).

    Article  CAS  Google Scholar 

  3. D. G. Shchukin, E. A. Ustinovich, A. I. Kulak, and D. V. Sviridov, Photochem. Photobiol. Sci. 3, 157 (2004).

    Article  CAS  Google Scholar 

  4. A. A. Belhekar, S. V. Awate, and R. Anand, Catal. Commun. 3, 453 (2002).

    Article  CAS  Google Scholar 

  5. Z. Ding, G. Q. Lu, and P. F. Greenfield, J. Colloid Interface Sci. 232, 1 (2000).

    Article  CAS  Google Scholar 

  6. S. I. Matsushita, T. Miwa, D. A. Tryk, and A. Fujishima, Langmuir 14, 6441 (1998).

    Article  CAS  Google Scholar 

  7. H. Haick and Y. Paz, J. Phys. Chem. B 105, 3045 (2001).

    Article  CAS  Google Scholar 

  8. A. Hattori, Y. Tokihisa, H. Tada, et al., J. Sol-Gel Sci. Technol. 22, 53 (2001).

    Article  CAS  Google Scholar 

  9. Y. Cao, X. Zhang, W. Yang, et al., Chem. Mater. 12, 3445 (2000).

    Article  CAS  Google Scholar 

  10. M. E. Zorn, D. T. Tomkins, W. A. Zeltner, and M. A. Anderson, Appl. Catal., B 23, 1 (1999).

    Article  CAS  Google Scholar 

  11. D. G. Shchukin, A. I. Kulak, and D. V. Sviridov, Photochem. Photobiol. Sci. 1, 742 (2002).

    Article  CAS  Google Scholar 

  12. E. N. Krut’ko and A. I. Kulak, Izv. Nats. Akad. Nauk Belarusi, Ser. Khim., No. 2, 44 (2006).

  13. M. E. Zorn, D. T. Tomkins, W. A. Zeltner, and M. A. Anderson, Environ. Sci. Technol. 34, 5206 (2000).

    Article  CAS  Google Scholar 

  14. C. Ooka, H. Yoshida, S. Takeuchi, et al., Catal. Commun. 5, 49 (2004).

    Article  CAS  Google Scholar 

  15. E. N. Krutsko and A. I. Kulak, in Nanomeeting-2005, May 24–27 (Minsk, 2005), pp. 413–416.

  16. V. F. Tikavyi and L. I. Tsukurova, Neorg. Mater. 1(1), 108 (1965).

    CAS  Google Scholar 

  17. C. B. Amphlett. Inorganic Ion Exchangers (Elsevier, Amsterdam, 1964; Mir, Moscow, 1966).

    Google Scholar 

  18. O. P. Stas’, R. Yu. Sheinfain, and V. M. Chertov, Ukr. Khim. Zh. 47(6), 609 (1981).

    CAS  Google Scholar 

  19. I. A. Bondar’ and A. E. Mal’shikov, Phosphates of Group Four Elements (Nauka, St. Petersburg, 1992) [in Russian].

    Google Scholar 

  20. S. E. Horsley, D. V. Nowell, and D. T. Stewart, Spectrochim. Acta, Part A 30, 535 (1974).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to E. N. Krut’ko.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Krut’ko, E.N., Galkova, T.N. & Kulak, A.I. Composite photocalysts based on the nanostructural titanium dioxide and zirconium phosphate. Russ. J. Phys. Chem. 82, 2219–2222 (2008). https://doi.org/10.1134/S0036024408130104

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036024408130104

Keywords

Navigation