Abstract
The chemistry of the surface and structural and adsorption properties of fluorinated carbon fiber were studied by IR spectroscopy, gas chromatography, and static adsorption of vapors and dyes from aqueous solutions. Also, the quantitative characteristics of the influence of a binder (polytetrafluoroethylene) used to prepare a granulated adsorbent on the basis of the fiber were determined. The functional properties of the adsorbent were found to be largely determined by the properties of the initial fluorocarbon fiber. Fluorocarbons were shown to possess a developed porous structure and highly hydrophobic chemically homogeneous nonpolar surface for the adsorption of most of the organic compounds studied.
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References
A. S. Fialkov, Carbon: Interlayer Compounds and Related Composites (Aspekt Press, Moscow, 1997) [in Russian].
Fluorine Compounds: Modern Technology and Application, Ed. by N. M. Ishikawa (Mir, Moscow, 1984) [in Russian].
H. Touhara and F. Okino, Carbon 38(2), 241 (2000).
Y. Sato, S. Shiraishi, Z. Mazej, et al., Carbon 41(10), 1971 (2003).
G. Nanse, E. Papirer, P. Fioux, et al., Carbon 35(2), 175 (1997).
M. Panich, A. I. Shames, and T. Nakajima, J. Phys. Chem. Solids 62(5), 959 (2001).
G. Li, K. Kaneko, S. Ozeki, et al., Langmuir 11, 716 (1995).
H. Touhara, J. Inahara, T. Mizuno, et al., J. Fluorine Chem. 114(2), 181 (2002).
B. V. Kuznetsov and A. A. Moreva, Zh. Fiz. Khim. 70(10), 1879 (1996) [Russ. J. Phys. Chem. 70 (10), 1745 (1996)].
T. M. Roshchina, N. K. Shonia, and S. V. Glazkova, Adsorption Sci. Technol. 23(7), 585 (2005).
T. M. Roshchina, S. V. Glazkova, N. A. Zubareva, and A. D. Khrycheva, Zh. Fiz. Khim. 81(2), 916 (2007) [Russ. J. Phys. Chem. A 81 (2), 277 (2007)].
A. V. Kiselev, Intermolecular Interactions in Adsorption and Chromatography (Vysshaya Shkola, Moscow, 1986) [in Russian].
N. V. Polyakova, A. E. Koldyshev, L. M. Pimenova, et al., RF Patent No. 2038594, Byull. Izobret., No. 18 (1995).
Experimental Methods in Adsorption and Molecular Chromatography, Ed. by A. V. Kiselev and V. P. Dreving (Mosk. Gos. Univ., Moscow, 1973) [in Russian].
T. D. Khokhlova, T. D. Ermakova, Yu. S. Nikitin, et al., Zh. Fiz. Khim. 69(11), 2017 (1995).
N. M. Ishikawa and Y. Kobayashi, Fluorine Compounds: Chemistry and Application (Kodansha Scientific, Tokyo, 1979; Mir, Moscow, 1982).
T. Nakajima, M. Koh, and V. Gupta, Electrochim. Acta 45, 1655 (2000).
V. M. Senyavin, I. V. Kochikov, and G. M. Kuramshina, J. Mol. Struct. 410–411, 463 (1997).
D. W. Brown, A. J. Floyd, and M. Sainsbury, Organic Spectroscopy (Wiley, Chichester, 1988; Mir, Moscow, 1992).
S. J. Gregg and K. S. W. Sing, Adsorption, Surface Area, and Porosity, 2nd ed. (Academic, New York, 1982; Mir, Moscow, 1984).
M. M. Dubinin, Adsorption and Porosity (VAKhZ, Moscow, 1972) [in Russian].
M. M. Dubinin, Izv. Akad. Nauk SSSR, Ser. Khim., p. 487 (1983).
T. V. Baikova, M. L. Gubkina, A. V. Larin, et al., Izv. Akad. Nauk, Ser. Khim., No. 9, 1544 (1993).
N. V. Kel’tsev, Fundamentals of Adsorption Engineering (Khimiya, Moscow, 1984) [in Russian].
A. V. Kiselev and Ya. I. Yashin, Gas Adsorption Chromatography (Nauka, Moscow, 1967) [in Russian].
A. A. Isirikyan and A. V. Kiselev, J. Phys. Chem. 65, 601 (1961).
P. J. M. Carrott, Carbon 30(2), 201 (1992).
A. M. Koganovskii, N. A. Klimenko, T. M. Levchenko, et al., in Adsorption of Organic Compounds from Water (Khimiya, Leningrad, 1990) [in Russian].
V. Ya. Davydov and T. D. Khokhlova, Zh. Fiz. Khim. 74(7), 1292 (2000) [Russ. J. Phys. Chem. 74 (7), 1162 (2000)].
E. V. Vlasenko, I. A. Godunov, S. N. Lanin, et al., Vestn. Mosk. Univ., Ser. 2: Khim. 46(4), 231 (2005).
N. N. Avgul’, A. V. Kiselev, and D. P. Poshkus, Adsorption of Gases and Vapors on Homogeneous Surfaces (Khimiya, Moscow, 1975) [in Russian].
E. V. Kalashnikova, A. V. Kiselev, A. M. Makogon, et al., Chromatografia 8(8), 399 (1975).
F. Bruner, G. Crescentini, and F. Mangani, Pure Appl. Chem. 61(11), 1997 (1989).
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Original Russian Text © N.A. Zubareva, T.M. Roshchina, T.D. Khokhlova, N.K. Shoniya, 2008, published in Zhurnal Fizicheskoi Khimii, 2008, Vol. 82, No. 12, pp. 2358–2366.
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Zubareva, N.A., Roshchina, T.M., Khokhlova, T.D. et al. Chemistry of the surface and structural and adsorption properties of fluorinated carbon fiber and an adsorbent based on it. Russ. J. Phys. Chem. 82, 2126–2133 (2008). https://doi.org/10.1134/S0036024408120273
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DOI: https://doi.org/10.1134/S0036024408120273