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Phase equilibria in the iodine-potassium iodide-water-propanol-2 four-component system

  • Chemical Thermodynamics and Thermochemistry
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Abstract

Isothermal-isobaric sections of the phase diagram of the iodine-potassium iodide-water-propanol-2 (2-C3H7OH) four-component system were studied at 25°C and atmospheric pressure. In all sections, threephase eutonic equilibria were observed with potassium iodide and crystalline iodine as solid phases. Potassium iodide was a iodine salting in agent in sections containing 15 and 25 wt % propanol-2 and a salting out agent in the section with 50 wt % alcohol. H2O-2-C3H7OH (85: 15 and 75: 25 wt %) mixed solvent compositions showed a higher ability to dissolve iodine than mixture components.

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Correspondence to G. V. Gerasimova.

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Original Russian Text © G.V. Gerasimova, T.M. Varlamova, S.P. Mushtakova, 2008, published in Zhurnal Fizicheskoi Khimii, 2008, Vol. 82, No. 12, pp. 2235–2238.

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Gerasimova, G.V., Varlamova, T.M. & Mushtakova, S.P. Phase equilibria in the iodine-potassium iodide-water-propanol-2 four-component system. Russ. J. Phys. Chem. 82, 2010–2013 (2008). https://doi.org/10.1134/S0036024408120066

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  • DOI: https://doi.org/10.1134/S0036024408120066

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