Skip to main content
Log in

The kinetics of heterogeneous nucleation in vapor-liquid phase transitions in the presence of ions

  • Chemical Thermodynamics and Thermochemistry
  • Published:
Russian Journal of Physical Chemistry A, Focus on Chemistry Aims and scope Submit manuscript

Abstract

A method for calculating the work of nucleus formation in vapor-liquid phase transitions in the presence of ions was suggested. The method took into account ions localized in the boundary surface layer of a nucleus. Analytic equations for nucleation frequency were obtained. The frequency of heterogeneous nucleation was calculated for supersaturated vapors of high-and low-polarity substances.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. G. V. Anikin and S. N. Plotnikov, Russ. J. Phys. Chem. 80(Suppl. 1), 85 (2006).

    Article  Google Scholar 

  2. G. V. Anikin and S. N. Plotnikov, Zh. Fiz. Khim. 79(2), 363 (2005) [Russ. J. Phys. Chem. 79 (2), 294 (2005)].

    Google Scholar 

  3. G. V. Anikin, Available from VINITI (Moscow, 2004), No. 218-V2004.

  4. G. V. Anikin, Available from VINITI (Moscow, 2005), No. 386-V2005.

  5. G. V. Anikin, Available from VINITI (Moscow, 2006), No. 657-V2006.

  6. R. F. Strickland-Constable, Kinetics and Mechanism of Crystallization (Academic, London, 1968; Nedra, Leningrad, 1971).

    Google Scholar 

  7. H. Rabeony and P. Mirabel, J. Phys. Chem. 91(7), 1815 (1987).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to G. V. Anikin.

Additional information

Original Russian Text © G.V. Anikin, L.S. Podenko, 2008, published in Zhurnal Fizicheskoi Khimii, 2008, Vol. 82, No. 12, pp. 2230–2234.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Anikin, G.V., Podenko, L.S. The kinetics of heterogeneous nucleation in vapor-liquid phase transitions in the presence of ions. Russ. J. Phys. Chem. 82, 2005–2009 (2008). https://doi.org/10.1134/S0036024408120054

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036024408120054

Keywords

Navigation