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The standard enthalpy of formation and low-temperature heat capacity of 1,1′,3,3′-tetra-(tert-butyl)ferrocene

  • Chemical Thermodynamics and Thermochemistry
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Abstract

The heat capacity of crystalline 1,1′,3,3′-tetra-(tert-butyl)ferrocene (TTBF) was measured in an adiabatic vacuum calorimeter over the temperature range 5–302 K. The thermodynamic functions of TTBF in the crystalline state were calculated from T→0 to 302 K. The enthalpy of combustion of TTBF was determined in an isothermal calorimeter with a stationary bomb. The standard thermodynamic functions of formation of the compound in the crystalline state at 298.15 K were calculated.

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Authors and Affiliations

  1. Lobachevsky Nizhni Novgorod State University, pr. Gagarina 23, Nizhni Novgorod, 630600, Russia

    M. S. Kozlova & N. V. Karyakin

  2. Research Institute of Chemistry, Lobachevsky Nizhni Novgorod State University, pr. Gagarina 23/5, Nizhni Novgorod, 603600, Russia

    V. N. Larina & M. S. Sheiman

Authors
  1. M. S. Kozlova
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  2. V. N. Larina
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  3. N. V. Karyakin
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  4. M. S. Sheiman
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Corresponding author

Correspondence to M. S. Kozlova.

Additional information

Original Russian Text © M.S. Kozlova, V.N. Larina, N.V. Karyakin, M.S. Sheiman, 2008, published in Zhurnal Fizicheskoi Khimii, 2008, Vol. 82, No. 12, pp. 2213–2217.

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Kozlova, M.S., Larina, V.N., Karyakin, N.V. et al. The standard enthalpy of formation and low-temperature heat capacity of 1,1′,3,3′-tetra-(tert-butyl)ferrocene. Russ. J. Phys. Chem. 82, 1988–1992 (2008). https://doi.org/10.1134/S0036024408120029

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  • DOI: https://doi.org/10.1134/S0036024408120029

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